On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Mr. W. Crookes discovered the new metal thallium by means of its
spectrum, which differs from every other in having one bright green line
upon a dark ground. He obtained its various salts, and the metal itself,
which he describes as being heavy, dense, and very like lead, but of
greater specific gravity. Its fresh surface has a bright metallic
lustre, not so blue as that of lead, but it tarnishes more easily. It is
so soft that it can be indented by the nail, yet it can be drawn into
wire, and in chemical properties it resembles mercury, lead, and
bismuth. Altogether it is more like a metal than a metalloid, perhaps
something between the two. Thallium is completely volatilized at a
temperature below red heat, whether single or in composition. If the
quantity be small, the green line appears in a sudden flash, lasting but
the fraction of a second. If a larger quantity of the metal be gradually
put into the flame, it lasts a little longer, appearing as a single
green line of extraordinary purity and intensity, sharply defined on a
black ground. With respect to volatility, thallium is analogous to the
non-metallic element selenium, which is so volatile that its beautiful
blue light only lasts a few seconds. The green light of thallium comes
out more rapidly, and with less of the substance, than the blue light of
selenium, a quantitative distinction which accords with Dr. Miller’s
observation that the rapidity with which a result is obtained, and the
minuteness of the quantity required for the examination, gives this
method a superiority over every other for the qualitative analysis of
the alkalies and alkaline earths. Thallium has been detected in mineral
waters, wine, treacle, tobacco, and chicory.
Drs. Reich and Richter discovered a fourth new metal in the zinc-blende
at Freiberg in Saxony, which has been called indium, from two beautiful
indigo-blue lines in its spectrum, which have a greater refrangibility
than the blue lines in strontium. The chemical relations of indium
resemble those of zinc, with which it is associated in nature. The metal
can be reduced before the blowpipe into a bead, which marks paper and
has the colour of tin.
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