On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
M. Bunsen thinks that there can hardly be a doubt of rubidium having
been mistaken for potassium, but he has shown that they may be
distinguished by the difference in the solubility of the double salts
which the chlorides of these two metals form with the chloride of
platinum. An aqueous solution of the bichloride of platinum and
potassium gives an insoluble yellow precipitate, consisting of the
bichlorides of platinum and potassium. An aqueous solution of the
bichlorides of platinum and rubidium gives an insoluble yellow
precipitate of the bichlorides of platinum and rubidium. These two
precipitates are undistinguishable to the eye. Now if a solution of
platinum be added to the first, no further precipitate can take place,
but if a solution of rubidium be added to it, a yellow precipitate is
formed consisting of the bichloride of rubidium and potassium, because
the chloride of rubidium resolves the precipitate, combines with the
chloride of potassium, and sets the chloride of platinum free. Thus the
precipitate of the bichloride of rubidium and potassium is the least
soluble of the two. The yellow colour is evidently due to the potassium.
Cæsium may be distinguished from potassium by the same process. The
carbonates, hydrates, and other salts of the two metals were determined;
their carbonates were shown to be readily separated, because the
carbonate of cæsium is soluble in alcohol, which the carbonate of
rubidium is not, and finally the metal rubidium was separated. It has an
extreme avidity for oxygen, and burns in water like potassium, and
possesses many other analogous qualities. It melts at the temperature of
38·5° Cent., and has a specific gravity of 1·516. Rubidium is abundant
in the mineral lepidolite in many parts of Europe and North America, and
M. Grandeau has detected it in the ashes of beetroot, tobacco, coffee,
tea, and grapes by spectrum analysis. It exists in various mineral
waters, and in fact is very general. Traces of various metals are met
with in the same vegetable; thus the spectrum of tobacco gives lines
characteristic of lithium, potassium, rubidium, and lime.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account