On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Providentially, chlorine is never found free; but in a combined state it
exists in enormous quantities in the salt of the ocean, in salt lakes,
brine springs, and in extensive deposits of rock-salt, as well as in
organic liquids. It has a strong affinity for hydrogen, and forms
muriatic acid. A mixture of these two gases remains inactive in the
dark, but explodes in sunshine.
By chemical means chlorine is made to combine with oxygen so as to
produce four substances, two of which are gases of such unstable
equilibrium and weak affinity that the slightest cause makes them
detonate violently; the other two are more stable, though they contain a
greater quantity of oxygen. The only combination of chlorine with
nitrogen is the most powerful and dangerous explosive compound known.
Chlorine combines naturally with sulphur, and with the metals so as to
form ores.
Common salt affords a remarkable instance of change of volume by
chemical combination. Twenty-four parts in bulk of salt contain 20·7
parts of sodium and 23·3 parts of liquid chlorine; hence by chemical
combination a bulk of 44 is compressed into a bulk of 24, yet that great
compression is consistent with perfect transparency, crystallized salt
being perfectly transparent to light, and more so as regards radiant
heat than any other substance. Thus chemical affinity does what no
mechanical power could accomplish.
At an ordinary temperature and barometric pressure, bromine is an orange
red, extremely volatile fluid, which congeals and becomes brittle at a
temperature a little below the zero of Fahrenheit’s thermometer, and if
combined with water at that degree of cold it crystallizes in octohedral
crystals which are permanent even at 50° Fahr. Bromine is very
poisonous, corrodes the skin, has a disagreeable taste, and a smell
similar to that of chlorine, but more pungent and hurtful. It possesses
a powerful bleaching property, does not conduct electricity, and like
chlorine a taper will not burn in its gas, though it spontaneously sets
fire to phosphorus, and some of the metals. Reasoning from analogy
Professor Schönbein believes that chlorine and bromine are not simple
substances; he considers them to be ozonides analogous to the peroxides
of manganese, lead, &c. He believes chlorine to be the peroxide of
murium, and bromine to be the peroxide of bromium. Professor Tyndall’s
experiments on the absorption and radiation of gases show that the
action of these two substances is very different from that of the simple
gases.
Public-domain text, read in full here on John Shaqi.
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