On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
This law leads to very important results. For example, the equivalent
weights of the chemical elements of bodies derived from their specific
gravities are either identical with, or simple multiples or
sub-multiples of, their relative weights. Thus the specific gravity of
hydrogen is 0·0693, and that of oxygen is 1·111; hence taking hydrogen
as the unit of comparison, it is easy to see that 0·0693 : 1·111 :: 1 :
16, the simple multiple of 8, the relative atomic weight of oxygen. In
fact since each substance has its own specific gravity or weight, that
weight must depend upon the weight of its atoms, so that the weights of
equal bulks of different substances are proportional to the weights of
their atoms, and thus a relation is established between the atomic
weights and specific gravities of bodies, so that one being given the
other may be found.
Atoms like their substances have many different capacities for heat and
electricity. It was proved by MM. Petit and Dulong, that specific heat,
or the quantity of heat required to raise a simple substance to a given
temperature, is inversely as the weight of its atoms, so that the
specific heat or repulsive force of simple substances multiplied by
their atomic weights is a constant quantity. Such is the condition
requisite for the equilibrium or equality of force; or the law may be
thus expressed: A given quantity of heat will raise to the same number
of degrees a portion of every simple substance represented by its atomic
weight. For instance, the atomic weight of sulphur is 16, that of zinc
32·5; hence it requires twice as much heat to raise a pound of sulphur
ten degrees as it does a pound of zinc. It has also been proved that the
atoms of compound bodies of analogous composition are endowed with the
same capacity for heat, so that there is a perfect correspondence
between the weight of atoms and their specific heat. The numbers
representing the atomic weights derived from the specific heat of bodies
are connected with their equivalent atomic weights by the simple ratios
of equality, multiples or sub-multiples.
Mr. J. Croll has made experiments showing that the specific heat of
compound gases and liquids is generally less, and those of solids more,
than that of their component elements, which is contrary to the hitherto
received opinion. Moreover it appears that the changes in the specific
heat of bodies which occur during combination are not only due to
chemical action, but also to molecular changes; the real specific heat
of a simple atom probably remaining the same under all conditions.
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