On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Mr. Faraday has proved that the specific electricity of different
substances is also in proportion to their atomic weights, that is to
say, a given quantity of electricity will separate combined substances
into parts represented by their atomic weights. For example, 32·5 parts
of zinc will generate voltaic electricity enough to separate nine parts
of water into eight parts of oxygen and one part of hydrogen gas. The
weights thus derived from decomposition are exactly the same with those
determined by composition, and thus the atomic weights derived from
electro-decomposition accord exactly with those obtained from chemical
composition. Moreover, Mr. Faraday, as already mentioned, proved that
the very same quantity of electricity necessary to decompose a body into
its elementary atoms, is requisite to unite them again. The analysis and
synthesis of compound matter, solid or fluid, show a constant and
definite proportion of the component elements expressed by number, and
by an equivalent or multiple ratio of parts in every chemical change.
The atomic theory unites, by a common bond, specific gravity, chemical
affinity, heat, and electricity. Taking atmospheric air at the
temperature of 60° Fahr. and a barometric pressure at 30 inches as the
standard unit of specific gravity; the quantity of heat required to
raise a volume of water 1° Fahr. as the unit of specific heat; hydrogen
gas as the unit of atomic weight; and atomic electro-chemical
electricity as the unit of specific electricity, the following numbers
have been established:
+----------+----------+------------+----------+-------------+
| | Specific | Equivalent | Specific | Specific |
| | gravity | atomic | heat | electricity |
| | | weight | | |
+----------+----------+------------+----------+-------------+
| Hydrogen | 0·0693 | 1 | 0·2936 | 1000 |
| Oxygen | 1·111 | 8 | 0·2361 | 125 |
| Carbon | 13·2 | 6 | 0·2631 | |
| Nitrogen | 0·978 | 14 | 0·2750 | |
+----------+----------+------------+----------+-------------+
The distances between the atoms of the gases are equal, hence the atomic
weights of simple gases are proportional to their densities; and for the
same reason, equal volumes of the same fluid contain an equal number of
atoms, and the number of atoms in the same volume of different fluids is
in the simple ratio of one to one, one to two, one to three, &c.
Public-domain text, read in full here on John Shaqi.
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