On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Transmutations of one isomeric substance for another may also be made in
organic bodies, but chlorine, bromine, and iodine form an exception to
M. Dumas’s law, because the arithmetical relation is wanting.
There are certain groups of substances, especially among the metals,
whose atomic weights are in regular arithmetical series, as those of
titanium, tin, and tantalum, which are 25, 59, and 92, the common
difference being 34.
Certain groups of combined atoms called compound radicles are much more
important than the preceding. They unite chemically with one another,
and with other substances in definite proportions, precisely as if they
were ultimate atoms. They are even capable of being substituted one for
the other, forming groups of infinitely varied properties, and thus
chemical equivalency extends to them.
Cyanogen, amidogen, and the peroxide of hydrogen are compound radicles
which combine with other substances and with simple atoms as if they
themselves were simple elements; though the first is a chemical compound
of two atoms of carbon and one of nitrogen, the second a chemical
compound of one atom of nitrogen and two of hydrogen, and the peroxide
contains as before mentioned two atoms of oxygen and one of hydrogen.
All three are capable of replacing hydrogen, chlorine, and metals by
equivalent substitutions. For example, the chlorate of potash consists
of one atom of potash, an atom of chlorine, and five atoms of oxygen; if
then an atom of cyanogen whose weight is 26, be put for the atom of
chlorine, the result would be the cyanate of potash.
Cyanogen, formed by passing nitrogen over red-hot carbon, consists of
two equivalents of carbon and one of nitrogen. It is a frequent
constituent of organic and inorganic compounds, and travels in the
voltaic circuit as if it were a simple substance.
Ammonia consists of three equivalents of hydrogen and one of nitrogen;
now, when the radical phenyle, which consists of twelve equivalents of
carbon and five of hydrogen, is put in the ammonia for one equivalent of
hydrogen, the result is aniline, whence most of the coal tar colours are
obtained. In like manner carbazotic acid, a beautiful yellow dye from
coal tar, is carbolic acid, three of whose equivalents of hydrogen have
been replaced by three equivalents of an oxide of nitrogen.
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