On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Successive substitution in isomeric bodies does not alter the character
of the chemical formulæ of these bodies; thus chlorine, bromine and
iodine, are chemically equivalent with an atom of hydrogen, for they may
be put for one or more atoms of hydrogen in various compounds without
changing the character of the chemical formulæ of these compounds. The
peroxide of hydrogen consists of one atom of hydrogen and two of oxygen;
hence if 32·5 parts of zinc, 28 of manganese, and 32 of copper be
successively put for the atom of hydrogen, the result will be the
peroxides of zinc, manganese and copper respectively. Here the character
of the chemical formula of the original compound remains the same, and
the three metals are chemically equivalent to one another, and to the
atom of hydrogen. In many compounds organic and inorganic, one or more
atoms of hydrogen may be replaced by an equal number of atoms of sodium,
potassium, zinc, &c., without altering the character of the chemical
formula of the compound.
Olefiant gas, olefiant oil and paraffin, form an isomeric series of a
gas, a liquid and a solid, consisting of carbon and hydrogen. The gas
contains 86 parts in 100 of carbon, and forms the most luminous part of
coal gas.
M. Dumas has proved it to be a general law, that when three isomeric
bodies are arranged in the sequence of their chemical properties, there
will also be a sequence in their respective atomic numbers, and that
whenever this symmetry of chemical properties and atomic weights
obtains, any one of these substances may be substituted for the other
without changing the chemical character of the formula.
Sulphur, selenium, and tellurium, form an isomeric group; that is, they
form a sequence, with analogous qualities, for sulphur is the most
volatile; selenium, a simple substance found in iron pyrites in Sweden,
is less volatile; and tellurium is the least volatile and with regard to
their atomic sequence, the atomic weight of sulphur is 16, that of
tellurium is 64, and half the sum of these numbers is 40, the atomic
weight of selenium, the mean term. Hence selenium might be put in any
compound for the sulphur, and the tellurium for the selenium, without
changing the chemical character of its formula.
The metallic group of calcium, strontium, and barium, are endowed with
analogous properties, perfect harmony in their chemical qualities, and
in the numbers expressing their atomic weights. That of calcium is 20,
that of barium is 68, and the half sum is 44, the atomic weight of
strontium. So calcium might be put for strontium, and strontium for
barium, in any compound without altering the character of its formula.
Professors Johnson and Allen have shown that the new metalloids cæsium
and rubidium form an isomeric triad with potassium, for the atomic
weight of cæsium is 133, that of rubidium 86, and that of potassium 39.
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