On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Dialysis is a method of separating and analysing substances by means of
their diffusion in alcohol or water. If a wide-mouthed vial nearly full
of a solution of common salt be placed in a jar of water, after a few
days it will be found that the particles of salt have come out of the
vial and have diffused themselves through the superincumbent water, even
to its surface. Now Professor Graham, Master of the Mint, with whom this
subject originated, made three arrangements precisely like that
described; the three vials were exactly similar and equal, the three
jars exactly the same in size and form, and contained the same quantity
of water; but the first vial contained a solution of gum arabic, the
second a solution of Epsom salt, and the third a solution of common
salt. After fourteen days the diffusion of the gum had risen through one
half of the superincumbent water, while the particles of both the salts
had risen to the surface. However the common salt would have risen much
higher, for when the strata of water at the two surfaces were drawn off
by a siphon and evaporated to dryness, there was fifteen times as much
common salt as Epsom salt. The three solutions are heavier than water,
yet they rise notwithstanding their gravitation, whence Mr. Graham
thinks that there is probably an attraction between the particles of the
dissolved substances and those of the water. The force of molecular
attraction is more powerful than gravitation, hence the particles must
rise by the difference of the two forces.
After many comparative experiments the professor concluded that most
substances differ in diffusibility, and that crystalloids or crystalline
substances such as salts, sugars, &c., are much more diffusible than
colloids or amorphous sticky bodies, such as gum, caramel, jellies, and
substances that combine with the hydrogen of the water to form
gelatinous hydrates.
The partial decomposition of definite chemical compounds may be effected
by diffusion. Alum, which is a double sulphate of the two metals
potassium and aluminium, furnishes an example; when allowed to diffuse
itself from its aqueous solution, the diffusive tendency of potassium
compounds is so much greater than the diffusive property of aluminium
compounds, that a portion of the sulphate of potassium actually breaks
away from the sulphate of aluminium with which it was combined, in order
to diffuse itself in the superincumbent external water more freely than
the sulphate of alumina can do.
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