On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Common salt diffuses itself in a solid mass of jelly almost as easily
and extensively as in the same bulk of free water. Thus colloid bodies
do not interfere with the diffusion of crystalloids such as salts, but
they almost entirely arrest the diffusion of one another. Solutions of
salts, sugars, and other crystalloids pass freely through colloid
substances, such as parchment-paper, vellum, and membrane into water,
although they have no pores, because the particles of the crystals unite
diffusively with the water combined in these substances, which solutions
of gum, caramel, and other colloids cannot do. These colloid substances
are permeable to solutions of crystalloids, impermeable to solutions of
colloids. This constitutes Dialysis.
The instrument used by Mr. Graham was a little tray formed of vellum or
membrane stretched tightly over a hoop of gutta-percha and capable of
holding a liquid and floating on water. When a mixed solution of equal
parts of salt and gum is put into the tray, after a time all the salt
will have passed into the water below, leaving nothing in the tray but
an aqueous solution of gum.
The following is one of the most extraordinary results of dialysis. Mr.
Graham took a silicate of soda, a soluble crystalline salt formed by
fusing quartz with carbonate of soda at a red heat, which diffuses
readily. He acidulated the aqueous solution of the salt with
hydrochloric acid, which changes the constituent silica from being a
crystalloid substance into a colloid form. When the liquid was poured
into the tray floating on water, after four days, the whole of the acid
and the chloride of sodium had been diffused in the water and nothing
remained in the tray but an aqueous solution of quartz. There remained
in fact, a solution of sand in water, a substance so hard that no pure
aqueous solution of it had ever been obtained. Many other crystalline
substances besides quartz can exist both in the colloid and crystalloid
states.
All colloid substances are characterized by non-crystalline habits, low
diffusibility, chemical inertness, high atomic weight, and above all by
their mutability. The aqueous solution of quartz is limpid and liquid,
even if it contains 14 per cent. of silica, but after a time it becomes
opalescent, viscous, and ultimately sets into a firm insoluble jelly,
capable however of solution by chemical means. This jelly gradually
shrinks, exudes pure water, and when perfectly dry it forms a glassy,
transparent, but not anhydrous substance, and the residue left by
ignition has a specific gravity of 2·2, that of crystallized silica
being 2·6.
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