On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The poisonous quality of coal gas is owing to the carbonic oxide, which
is fatal to life, and its explosive quality to carburetted hydrogen,
which also is generated by decomposition of vegetable matter in stagnant
pools and marshes; and in the firedamp of mines it still bears testimony
to the vegetable origin of coal. That fatal gas increases in explosive
force as it mixes with atmospheric air, and is at a maximum when it
amounts to 12 per cent. Hydrogen, carburetted hydrogen, and carbonic
oxide do not add much to the light, on account of the feeble flame of
hydrogen and the small quantity of carbon they contain, but they force
the chief illuminating gases out of the iron retorts in which the coal
is distilled before the heat has had time to decompose them, and they
also enable them to burn without smell or smoke.
Carbonic acid, bisulphide of carbon, and sulphuretted hydrogen are
impurities from which coal gas is freed before it is fit for use. By
passing the gas over lime, the lime absorbs both the carbonic acid and
the sulphuretted hydrogen; one per cent. of carbonic acid diminishes the
illuminating power six per cent., and the sulphuretted hydrogen has an
abominable smell.
The bisulphide of carbon, consisting of one equivalent of carbon and two
of sulphur, is got rid of by passing the gas over hot lime. The water of
the lime is decomposed, and carbonic oxide and sulphuretted hydrogen are
produced; but the latter may be absorbed by passing the gas again over
lime, or through a mixture of sawdust and the oxide of iron. The oxide
of iron decomposes the sulphuretted hydrogen, forms water and sulphide
of iron, then the air restores the sulphide to oxide, and the sulphur is
deposited in the mixture. After passing the gas through it till none of
that impurity remains, the gas is fit for use. The test is the
nitro-prusside of sodium, which the gas stains purple if any of the
impurity remains.
Paraffin, already mentioned as isomeric, is a pure hydrocarbon,
colourless, transparent, and of crystalline texture. It melts at a heat
of 120° or 130°, burns like wax without smell or smoke, and makes
beautiful candles, which give a brilliant light on account of the 86 per
cent. of carbon they contain. Paraffin oil is much used for lamps; the
manufacture of these two substances at Bathgate is one of the largest
chemical establishments in the world.
The black fœtid gas water resulting from the distillation of coals,
formerly thrown away, is so rich in the salts of ammonia, that it has
become the chief source from which these materials so important in the
arts are obtained.
Ammonia is well known to be a colourless gas, with an acrid pungent
smell, consisting of one equivalent of nitrogen and three of hydrogen.
It has an alkaline character, combining with acids, and is extremely
soluble in water.
Public-domain text, read in full here on John Shaqi.
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