On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Now the gas water contains carbonate of ammonia and sulphide of
ammonium, and when any acid strong enough to decompose these substances
is put into the liquid, the carbonic acid and sulphuretted hydrogen
being volatile are driven off, and the acid combines with the ammonia to
form a salt. For example, when muriatic acid is put into the liquid, it
drives off the volatile gases and combines with the ammonia in solution
to form muriate of ammonia, which is dissolved in water and evaporated
till it crystallises; then it is vaporized and sublimed to free it from
impurities.
When ammonia and muriatic acid are separately vaporized, the two
colourless transparent vapours, when mixed, combine into solid muriate
of ammonia, a result so unexpected that as Mr. Playfair justly observes,
it could only have been taught by experiment. About 4,000 tons of
muriate of ammonia are annually made from gas water in England for
soldering, and for making alum.
Sulphate of ammonia to the extent of 5,000 tons is annually made by
adding oil of vitriol to the liquid. It is also used for making alum, as
well as for manure; it supplies our grain with nitrogen, an important
article of vegetable food. To these may be added 2,000 tons of carbonate
of ammonia, so that a substance that was considered to be good for
nothing yields 11,000 tons of valuable materials, but even this quantity
forms only part of the enormous amount annually consumed in the
manufactures of Great Britain.
Coal tar is of complicated nature, containing a variety of substances,
many of which are more or less volatile. When it is distilled by sending
a current of steam through it, the steam collects the volatile parts,
condenses them into naphtha; the first product is condensed steam or
water with naphtha swimming on its surface, the next product is dead
oil, and the remainder is pitch.
By the aid of the crude naphtha thus produced, Indian rubber is
dissolved and waterproof clothes are made. When purified by sulphuric
acid, it forms a substance like tar which is thrown away, and the
remaining products when clarified are acid oils and neutral
hydro-carbons. The carbolic and cressylic acids are the most important
of these acid oils. The carbolic acid, which has the property of
arresting the putrefaction and decay of organic matter, consists of 12
equivalents of carbon, 6 of hydrogen, and 2 of oxygen. The cressylic
acid only differs from the preceding by having two more equivalents of
hydrogen and two of oxygen in its chemical composition.
Creosote is a mixture of these two acids. Those vast beams of wood that
are driven as piles into the sand or mud at the bottom of the sea, as
well as the timbers that form marine superstructures, are saturated with
it to a certain depth to preserve them from the attacks of marine
insects, especially Limnoria terebrans, an isopod crustacean, which is
so destructive in some of our harbours. The wood is deprived of its air
by heat and the creosote easily enters.
Public-domain text, read in full here on John Shaqi.
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