On Sulphonfluoresceïn and Some of Its Derivatives — John Shaqi
On Sulphonfluoresceïn and Some of Its DerivativesHayes, C. W. (Charles Willard)
Science
On Sulphonfluoresceïn and Some of Its Derivatives
Hayes, C. W. (Charles Willard)
Sulfonefluorescein; Thesis (Ph. D.)
It does not melt at 250° but if held at a lower temperature for a
long time becomes red undergoing some decomposition. If quickly
heated somewhat above 300° it melts to a deep red liquid and then
solidifies. If the mass is treated with water it partly dissolves
leaving a dark brown flocculent precipitate which dissolves on the
addition of an alkali, the solution having an intense fluorescence,
nearly if not quite equaling that of fluoresceïn. This change
produced by heating was not further studied.
The crystals are very thin blades, apparently monoclinic, showing the
clinopinacoid αΡὰ and a very narrow prism αΡ and clinodome Ρὰ. The
angle β = 75° and the extinction angle against the ϲ axis = 20°.
The axial ratio could not be accurately determined.
Salts of sulphonfluoresceïn.
The influence of the SO_{2} group is shown by the fact that the
substance acts as an acid decomposing carbonates and forming salts
which is not the case with fluoresceïn.
Barium salt.
The substance was boiled with an excess of carefully purified
BaCO_{3} for two hours. The filtrate from the BaCO_{3} evaporated
to a small volume deposited yellow crystals resembling the original
substance but in shorter and thicker prisms. These were twice
recrystallized and had then a light straw yellow color.
A determination of the Ba gave the following results. The salt was
dried in the air.
[Transcriber’s Note:
The following table was crossed out on the original.
A note on the previous page beside the table was:
All these calculations are wrong.
J.R.]
I ·1078 gr salt gave ·0304 gr BaSO_{4} = 15·73% Ba.
II ·1641 ” ” ” ·0457 ” ” = 15·53” ”
III ·2425 ” ” ” ·0680 ” ” = 15·65” ”
IV ·2860 ” ” ” ·0798 ” ” = 15·54” ”
V ·1843 ” ” ” ·0498 ” ” = 15·08” ”
VI ·2620 ” ” ” ·0708 ” ” = 15·08” ”
VII ·3230 ” ” ” ·0906 ” ” = 15·65” ”
VIII ·2875 ” ” ” ·0807 ” ” = 15·66” ”
Calculated for C_{19}H_{13}O_{7}SBa = 15·10% Ba.
In the above determinations the salt analysed was taken from
specimens made at three different times and purified in slightly
different ways, Nos 1, 2, & 3 being washed with absolute alcohol. Nos
V and V were made by precipitating the Ba with H_{2}SO_{4} from a
solution of the salt.
The water was determined by heating at 110° till constant weight was
reached. Part only of the weight lost was regained on standing in the
air.
·3943 gr salt lost at 110° ·0286 gr = 7.25%
Water calculated for C_{19}H_{13}O_{7}SBa+2H_{2}O = 7.35%
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