On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
figure when put back again into the solution of alum, which shows that
the internal and external particles are similar, and have a similar
attraction for the particles held in solution. The original conditions
of aggregation which make the molecules of the same substance unite in
different forms must be very numerous, since of carbonate of lime alone
there are many hundred varieties; and certain it is, from the motion of
polarised light through rock crystal, that a very different arrangement
of particles is requisite to produce an extremely small change in
external form. A variety of substances in crystallising combine
chemically with a certain portion of water which in a dry state forms an
essential part of their crystals, and, according to the experiments of
MM. Haidinger and Mitscherlich, seems in some cases to give the peculiar
determination to their constituent molecules. These gentlemen have
observed that the same substance crystallising at different temperatures
unites with different quantities of water and assumes a corresponding
variety of forms. Seleniate of zinc, for example, unites with three
different portions of water, and assumes three different forms,
according as its temperature in the act of crystallising is hot,
lukewarm, or cold. Sulphate of soda also, which crystallises at 90° of
Fahrenheit without water of crystallisation, combines with water at the
ordinary temperature, and takes a different form. Heat appears to have a
great influence on the phenomena of crystallisation, not only when the
particles of matter are free, but even when firmly united, for it
dissolves their union, and gives them another determination. Professor
Mitscherlich found that prismatic crystals of sulphate of nickel
(N. 164), exposed to a summer’s sun in a close vessel, had their
internal structure so completely altered without any exterior change,
that when broken open they were composed internally of octahedrons with
square bases. The original aggregation of the internal particles had
been dissolved, and a disposition given to arrange themselves in a
crystalline form. Crystals of sulphate of magnesia and of sulphate of
zinc, gradually heated in alcohol till it boils, lose their transparency
by degrees, and when opened are found to consist of innumerable minute
crystals totally different in form from the whole crystals; and
prismatic crystals of zinc (N. 165) are changed in a few seconds into
octahedrons by the heat of the sun: other instances might be given of
the influence of even moderate degrees of temperature on molecular
attraction in the interior of substances. It must be observed that these
experiments give entirely new views with regard to the constitution of
solid bodies. We are led from the mobility of fluids to expect great
changes in the relative positions of their molecules, which must be in
perpetual motion even in the stillest water or calmest air; but we were
not prepared to find motion to such an extent in the interior of solids.
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