On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
That their particles are brought nearer by cold and pressure, or removed
farther from one another by heat, might be expected; but it could not
have been anticipated that their relative positions could be so entirely
changed as to alter their mode of aggregation. It follows, from the low
temperature at which these changes are effected, that there is probably
no portion of inorganic matter that is not in a state of relative
motion.
Professor Mitscherlich’s discoveries with regard to the forms of
crystallised substances, as connected with their chemical character,
have thrown additional light on the constitution of material bodies.
There is a certain set of crystalline forms which are not susceptible of
variation, as the die or cube (N. 166), which may be small or large, but
is invariably a solid bounded by six square surfaces or planes. Such
also is the tetrahedron (N. 167) or four-sided solid contained by four
equal-sided triangles. Several other solids belong to this class, which
is called the Tessular system of crystallisation. There are other
crystals which, though bounded by the same number of sides, and having
the same form, are yet susceptible of variation; for instance, the
eight-sided figure with a square base, called an octahedron (N. 168),
which is sometimes flat and low, and sometimes acute and high. It was
formerly believed that identity of form in all crystals not belonging to
the Tessular system indicated identity of chemical composition.
Professor Mitscherlich, however, has shown that substances differing to
a certain degree in chemical composition have the property of assuming
the same crystalline form. For example, the neutral phosphate of soda
and the arseniate of soda crystallise in the very same form, contain the
same quantities of acid, alkali, and water of crystallisation; yet they
differ so far, that one contains arsenic and the other an equivalent
quantity of phosphorus. Substances having such properties are said to be
isomorphous, that is, equal in form. Of these there are many groups,
each group having the same form, and similarity though not identity of
chemical composition. For instance, one of the isomorphous groups is
that consisting of certain chemical substances called the protoxides of
iron, copper, zinc, nickel, and manganese, all of which are identical in
form and contain the same quantity of oxygen, but differ in the
respective metals they contain, which are, however, nearly in the same
proportion in each. All these circumstances tend to prove that
substances having the same crystalline form must consist of ultimate
atoms having the same figure and arranged in the very same order; so
that the form of crystals is dependent on their atomic constitution.
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