On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
The disturbance of electric equilibrium, and a development of
electricity, invariably accompany the chemical action of a fluid on
metallic substances, and the electricity is most plentiful when that
action occasions oxidation. Metals vary in the quantity of electricity
afforded by their combination with oxygen. But the greatest abundance is
developed by the oxidation of zinc by weak sulphuric acid. And, in
conformity with the law that one kind of electricity cannot be evolved
without an equal quantity of the other being brought into activity, it
is found that the acid is positively, and the zinc negatively electric.
It has not yet been ascertained why equilibrium is not restored by the
contact of these two substances, which are both conductors, and in
opposite electrical states. However, the electrical and chemical changes
are so connected, that, unless equilibrium be restored, the action of
the acid will go on languidly, or stop as soon as a certain quantity of
electricity is accumulated in it. Equilibrium, nevertheless, will be
restored, and the action of the acid will be continuous, if a plate of
copper be placed in contact with the zinc, both being immersed in the
fluid; for the copper, not being acted upon by the acid, will serve as a
conductor to convey the positive electricity from the acid to the zinc,
and will at every instant restore the equilibrium, and then the
oxidation of the zinc will go on rapidly. Thus three substances are
concerned in forming a Voltaic circuit, but it is indispensable that one
of them should be a fluid. The electricity so obtained will be very
feeble in overcoming resistances offered by imperfect conductors
interposed in the circuit, or by very long wires, but it may be
augmented by increasing the number of plates. In the common Voltaic
battery, the electricity which the fluid has acquired from the first
plate of zinc exposed to its action is taken up by the copper plate
belonging to the second pair, and transferred to the second zinc plate,
with which it is connected. The second plate of zinc, possessing equal
powers, and acting in conformity with the first, having thus acquired a
larger portion of electricity than its natural share, communicates a
larger quantity to the fluid in the second cell. This increased quantity
is again transferred to the next pair of plates; and thus every
succeeding alternation is productive of a further increase in the
quantity of the electricity developed. This action, however, would stop
unless a vent were given to the accumulated electricity, by establishing
a communication between the positive and negative poles of the battery
by means of wires attached to the extreme plate at each end. When the
wires are brought into contact, the Voltaic circuit is completed, the
electricities meet and neutralize each other, producing the shock and
other electrical phenomena; and then the electric current continues to
flow uninterruptedly in the circuit, as long as the chemical action
lasts.
Public-domain text, read in full here on John Shaqi.
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