On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
The stream of positive electricity flows from the zinc to the
copper. The construction and power of the Voltaic battery have been much
improved of late years, but the most valuable improvement is the
constant battery of Professor Daniell. In all batteries of the ordinary
construction, the power, however energetic at first, rapidly diminishes,
and ultimately becomes very feeble. Professor Daniell found that this
diminution of power is occasioned by the adhesion of the evolved
hydrogen to the surface of the copper, and by the precipitation of the
sulphate formed by the action of the acid on the zinc. He prevents the
latter by interposing between the copper and the zinc, in the cell
containing the liquid, a membrane which, without impeding the electric
current, prevents the transfer of the salt; and the former, by placing
between the copper and the membrane solution of sulphate of copper,
which being reduced by the hydrogen prevents the adhesion of this gas to
the metallic surface. Each element of the battery consists of a hollow
cylinder of copper, in the axis of which is placed a cylindrical rod of
zinc; between the zinc and the copper a membranous bag is placed, which
divides the cell into two portions, the inner of which is filled with
dilute acid, and the one nearer the copper is supplied with crystals of
the sulphate of that metal. The battery consists of several of these
elementary cells connected together by metallic wires, the zinc rod of
one with the copper cylinder of that next to it. The zinc rods are
amalgamated, so that local action, which, in ordinary cases, is so
destructive of the zinc, does not take place, and no chemical action is
manifested unless the circuit be completed. The rods are easily
detached, and others substituted for them when worn out. This battery,
which possesses considerable power, and is constant in its effects for a
very long time, is greatly superior to all former arrangements, either
as an instrument of research, or for exhibiting the ordinary phenomena
of Voltaic electricity.
A battery charged with water alone, instead of acid, is constant in its
action, but the quantity of electricity it develops is comparatively
very small. Mr. Cross, of Broomfield in Somersetshire, kept a battery of
this kind in full force during twelve months. M. Becquerel had invented
an instrument for comparing the intensities of the different kinds of
electricity by means of weights; but, as it is impossible to make the
comparison with Voltaic electricity produced by the ordinary batteries,
on account of the perpetual variation to which the intensity of the
current is liable, he has constructed a battery which affords a
continued stream of electricity of uniform power, but it is also of very
feeble force. The current is produced by the chemical combination of an
acid with an alkali.
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