On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
progress. But it is now proved to be as efficacious in the composition
as in the decomposition or analysis of bodies.
It had been observed that, when metallic solutions are subjected to
galvanic action, a deposition of metal, sometimes in the form of minute
crystals, takes place on the negative wire. By extending this principle,
and employing a very feeble Voltaic action, M. Becquerel has succeeded
in forming crystals of a great proportion of the mineral substances,
precisely similar to those produced by nature. The electric state of
metallic veins makes it possible that many natural crystals may have
taken their form from the action of electricity bringing their ultimate
particles, when in solution, within the narrow sphere of molecular
attraction. Both light and motion favour crystallization. Crystals which
form in different liquids are generally more abundant on the side of the
jar exposed to the light; and it is well known that still water, cooled
below 32°, starts into crystals of ice the instant it is agitated. A
feeble action is alone necessary, provided it be continued for a
sufficient time. Crystals formed rapidly are generally imperfect and
soft, and M. Becquerel found that even years of constant Voltaic action
were necessary for the crystallization of some of the hard substances.
If this law be general, how many ages may be required for the formation
of a diamond!
The deposition of metal from a metallic solution by galvanic electricity
has been most successfully applied to the arts of plating and gilding,
as well as to the more delicate process of copying medals and copper
plates. Indeed, not medals only, but any object of art or nature, may be
coated with precipitated metal, provided it be first covered with the
thinnest film of plumbago, which renders a non-conductor sufficiently
conducting to receive the metal. Photo-galvanic engraving depends upon
this. Gelatine mixed with bichromate of potash, nitrate of silver, and
iodide of potassium, is spread over a plate of glass, and when dry a
positive print is laid upon it with its face downwards, which, when
exposed to the sun, leaves its impression. When soaked in water the
gelatine swells around all those parts where the light had fallen, thus
forming an intaglio, a cast of which is taken in gutta-percha, which is
then coated with copper by the electro process, whence a copper plate in
relief is obtained.
Public-domain text, read in full here on John Shaqi.
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