On the Connexion of the Physical SciencesSomerville, Mary
Science
On the Connexion of the Physical Sciences
Somerville, Mary
Physical sciences; Science
Voltaic electricity is a powerful agent in chemical analysis. When
transmitted through conducting fluids, it separates them into their
constituent parts, which it conveys in an invisible state through a
considerable space or quantity of liquid to the poles, where they come
into evidence. Numerous instances might be given, but the decomposition
of water is perhaps the most simple and elegant. Suppose a glass tube
filled with water, and corked at both ends; if one of the wires of an
active Voltaic battery be made to pass through one cork, and the other
through the other cork, into the water, so that the extremities of the
two wires shall be opposite and about a quarter of an inch asunder,
chemical action will immediately take place, and gas will continue to
rise from the extremities of both wires till the water has vanished. If
an electric spark be then sent through the tube, the water will
reappear. By arranging the experiment so as to have the gas given out by
each wire separately, it is found that water consists of two volumes of
hydrogen and one of oxygen. The hydrogen is given out at the positive
wire of the battery, and the oxygen at the negative. The oxides are also
decomposed; the oxygen appears at the positive pole, and the metal at
the negative. The decomposition of the alkalies and earths by Sir
Humphry Davy formed a remarkable era in the history of science. Soda,
potash, lime, magnesia, and other substances heretofore considered to be
simple bodies incapable of decomposition, were resolved by electric
agency into their constituent parts, and proved to be metallic oxides,
by that illustrious philosopher. All chemical changes produced by
electricity are accomplished on the same principle; and it appears that,
in general, combustible substances, metals, and alkalies go to the
negative wire, while acids and oxygen are evolved at the positive. The
transfer of these substances to the poles is not the least wonderful
effect of the Voltaic battery. Though the poles be at a considerable
distance from one another, nay, even in separate vessels, if a
communication be only established by a quantity of wet thread, as the
decomposition proceeds the component parts pass through the thread in an
invisible state, and arrange themselves at their respective poles.
According to Dr. Faraday, electro-chemical decomposition is simply a
case of the preponderance of one set of chemical affinities more
powerful in their nature over another set which are less powerful. And
in electro-chemical action of any kind produced by a continuous current,
the amount of action in a given time is nearly, if not rigorously,
proportional to the strength of the current. The great efficacy of
Voltaic electricity in chemical decomposition arises not from its
tension, but from the quantity set in motion and the continuance of its
action. Its agency appears to be most exerted on fluids and substances
which by conveying the electricity partially and imperfectly impede its
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