On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
From these experiments it is clear that the oxidation phenomena which
Hoppe-Seyler and Baumann attributed to active oxygen are really due to
the combined action of palladium and hydrogen dioxide, and to suppose
that atomic oxygen exists in the free state at any time during the
process is entirely gratuitous.
It remained to test the second of Baumann’s statements; namely that
carbon monoxide in the presence of moist phosphorus and air is oxidized
to carbon dioxide by the active oxygen formed by the slow combustion
of the phosphorus. Leeds[24] also has on record an experiment on this
subject, in which he claims that under these conditions oxidation takes
place. In taking up the subject, therefore, Prof. Remsen[25] and myself
have taken the greatest care to avoid all sources of error. We tried
the effects of passing air alone freed from carbon dioxide over moist
phosphorus and then into clear baryta water, Baumann[26] states that
this can be done, and the baryta water remains perfectly clear, even if
the current of air is passed for six hours. We obtained a precipitate
immediately. Thinking this might be caused by the white vapors which
are formed during the process, we passed the gas after its exit from
the vessel containing the phosphorus through a layer of previously
ignited asbestos. The layer of asbestos was between two and three feet
in length and the air after having traversed it no longer contained
any white fumes. From the asbestos tube the air passed into a solution
of clear baryta water. A precipitate was formed at once and increased
in quantity the longer the current continued. “It was tested for
phosphoric acid and phosphorus in general but not a trace could
be detected. The current of air over the phosphorus was continued
for several days in order to obtain enough of the precipitate for
examination and analysis. It proved to be nothing but barium carbonate.”
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