On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
That ordinary commercial sticks of phosphorus contain carbon was shown
by us in the following way[30]:--Air was passed from a gasometer into a
hard glass tube containing copper oxide heated to redness, represented
by K in the drawing. Then through a series of wash bottles A, B, C, so
constructed that the connecting tubes were fitted into each other by
means of ground glass joints. A and B contained a concentrated solution
of caustic soda, C a solution of baryta water. The air then passed into
an ordinary bell jar, having a capacity of about a litre and a quarter.
This was held in position on mercury contained in a crystallizing dish.
The inlet tube was bent downward into a small dish containing the
phosphorus, represented by H in the figure. The gas after leaving the
bell jar passed through two wash bottles D and E, similar to A, B, C. D
contained 30-40 c.c. of ordinary distilled water. E contained a clear
solution of baryta water, and was connected with a tube containing
solid caustic potash to protect it from the air. The outlet tube from
the wash bottle C is bent so as to pass beneath the edge of the bell
jar, then up into the closed space above the mercury, and then down
towards the phosphorus. A long funnel tube J served to introduce or
remove water from the dish containing the phosphorus. The air therefore
after having entered the tube K came at no point in contact with
organic matter, and yet we found that after all ordinary air had been
displaced by purified air, and clear baryta water introduced into
the wash bottle E, a precipitate was found. Ten litres of air were
sufficient to cause a distinct turbidity, while 20 to 30 gave a
precipitate. As there is no possible source of error it follows
that the carbon dioxide must have come from the oxidation of carbon
contained in the phosphorus.
[Illustration]
That carbon should be present in phosphorus is not surprising
considering its method of manufacture. Whether the carbon existing in
the phosphorus is in chemical combination or not we are unable to say.
The specimens of phosphorus used by us were perfectly homogenous. There
was no evidence of the presence of particles in them, and the solution
in carbon bisulphide was perfectly clear, and on standing nothing
whatever was deposited. Even distilled phosphorus acted in the same
way, showing that this also contained carbon.
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