On the various forces of nature and their relations to each otherFaraday, Michael
Science
On the various forces of nature and their relations to each other
Faraday, Michael
Physics
Now, this chemical action is set going exactly as it would be if I
had lighted the candle, or as it is when the servant puts coals on
and lights the fire: the substances wait until we do something which
is able to start the action. Can anything be more beautiful than this
combustion of charcoal in oxygen? You must understand that each of
these little sparks is a portion of the charcoal, or the bark of the
charcoal, thrown off white-hot into the oxygen, and burning in it most
brilliantly, as you see. And now let me tell you another thing, or you
will go away with a very imperfect notion of the powers and effects of
this affinity. There you see some charcoal burning in oxygen. Well, a
piece of lead will burn in oxygen just as well as the charcoal does,
or indeed better; for absolutely that piece of lead will act at once
upon the oxygen as the copper did in the other vessel with regard to
the chlorine. And here also a piece of iron: if I light it and put
it into the oxygen, it will burn away just as the carbon did. And I
will take some lead, and shew you that it will burn in the common
atmospheric oxygen at the ordinary temperature. These are the lumps of
lead which, you remember, we had the other day--the two pieces which
clung together. Now these pieces, if I take them to-day and press them
together, will not stick; and the reason is, that they have attracted
from the atmosphere a part of the oxygen there present, and have
become coated as with a varnish by the oxide of lead, which is formed
on the surface by a real process of combustion or combination. There
you see the iron burning very well in oxygen; and I will tell you the
reason why those scissors and that lead do not take fire whilst they
are lying on the table. Here the lead is in a lump, and the coating of
oxide remains on its surface; whilst there you see the melted oxide
is clearing itself off from the iron, and allowing more and more to
go on burning. In this case, however [holding up a small glass tube
containing lead pyrophorus.[20]], the lead has been very carefully
produced in fine powder, and put into a glass tube, and hermetically
sealed, so as to preserve it; and I expect you will see it take fire
at once. This has been made about a month ago, and has thus had time
enough to sink down to its normal temperature. What you see, therefore,
is the result of chemical affinity alone. [The tube was broken at
the end, and the lead poured out on to a piece of paper, whereupon it
immediately took fire.] Look, look at the lead burning; why, it has set
fire to the paper! Now, that is nothing more than the common affinity
always existing between very clean lead and the atmospheric oxygen; and
the reason why this iron does not burn until it is made red-hot is,
because it has got a coating of oxide about it, which stops the action
of the oxygen--putting a varnish, as it were, upon its surface, as we
varnish a picture, absolutely forming a substance which prevents the
Public-domain text, read in full here on John Shaqi.
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