Our Atomic World: The Story of Atomic EnergyCraven, C. Jackson (Claude Jackson)
History
Our Atomic World: The Story of Atomic Energy
Craven, C. Jackson (Claude Jackson)
Nuclear energy -- Popular works
Rutherford’s discovery aroused intense curiosity about the nature and
possible structure of this extremely small, but all-important, part of
an atom. It was assumed that the positive charge carried by the nucleus
must be a whole-number multiple of a small unit equal in size but
opposite in sign to the charge of an electron. This conclusion was based
on the information that all atoms contain electrons and that an
undisturbed atom is electrically neutral. Since it was known that a
neutral atom of hydrogen contains just one electron, it appeared that
the charge on a hydrogen nucleus must represent the fundamental unit of
positive charge, some multiple of which would represent the charge on
any other nucleus. Several lines of investigation combined to establish
quite firmly that nuclei of atoms occupying adjacent positions on the
periodic chart of the elements differed in charge by this fundamental
unit. Since the hydrogen nucleus seemed to play such an important role
in making up the charges of all other nuclei, it was given the name
proton from the Greek “protos,” which means “first.”
Isotopes Are Discovered
At a historic meeting of the British Association for the Advancement of
Science held in Birmingham, England, in 1913, two apparently unrelated
lines of investigation were reported, each of which showed that some
atomic nuclei have identical electric charges but different weights.
One report was presented by Frederick Soddy, who had collaborated with
Rutherford in explaining the pattern of natural radioactivity. Soddy
knew that the nucleus of a radioactive atom loses both weight and
positive charge when it throws out an alpha particle (helium nucleus).
On the other hand, when a nucleus emits a beta particle (negative
electron), its positive charge increases, but its weight is practically
unchanged. Thus Soddy could deduce the weights and nuclear charges of
many radioactive products. In several cases the products of two
different kinds of radioactivity had the same nuclear charge but
different weights. Since it is the positive charge carried by the
nucleus of an atom which fixes the number of negative electrons needed
to complete the atom, the nuclear charge is really responsible for the
exterior appearance, or chemical properties, of the atom.
This conclusion was confirmed by unsuccessful efforts to separate by
chemical means different radioactive products having the same nuclear
charge but different weights. The products might have had quite
different rates of radioactive disintegration, but they appeared to
consist of chemically identical atoms of the same chemical element and
hence to belong at the _same place_ on the periodic chart of the
elements. Soddy suggested that such atoms be called _isotopes_, from a
Greek word meaning “same place.”
Public-domain text, read in full here on John Shaqi.
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