Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
[25] A brief study of the theory of solutions (See Cushman and Gardner
on "Corrosion and Preservation of Iron and Steel"), involving the
modes of iron formation, will be invaluable to the student who is
inquiring into the cause of the peculiar fogging of lithopone,
with the idea in view of correcting this evil by physical or
chemical treatment. Inasmuch as our observations thus far have
led us to believe that the fogging of lithopone takes place in
the presence of moisture, with the contributory and necessary
action of chemically active rays from the sun or other source, it
is fair to assume that under these conditions the insoluble
molecule of zinc sulphide and barium sulphate reverts by
intricate molecular disturbance and ionization back to the
soluble barium sulphide and zinc sulphate from which the
lithopone is formed by metathesis. If this be true, then the acid
nature of these soluble salts is no doubt combated and overcome
at the moment of formation by the basic nature of zinc oxide and
calcium carbonate, which tend to ionize to an alkaline reaction.
The value of zinc oxide and calcium carbonate in lithopone paints
as detergents of blackness, has been demonstrated at both
Atlantic City and Pittsburg." H. A. G.
[Illustration: Section of Fence Showing New Panels Recently Placed]
[Illustration: Appearance of 1909 Tests]
An inspection of these new tests was made during June, 1910, and the
results of the inspection are shown on pages 178 to 181. The results of
the inspection prove that it is unsafe to use lithopone in a paint
containing white lead of any type, early darkening and failure being
shown in every case where such a combination existed. The formulas in
the new test, which were properly balanced and which had a low
percentage of lithopone combined with zinc oxide and whiting, presented
in some cases very good surfaces. A rough, sandy surface, however, was
shown where lithopone was used in any great quantity.
TESTS INAUGURATED IN 1909
RESULTS OF INSPECTION OF ATLANTIC CITY TEST FENCE, MAY, 1910
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