Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
The longevity of lampblack and carbon black paint films when applied to
wood has been attributed to the slow drying nature of these pigments
when mixed with oil. It is assumed that they have the property of
keeping the oil in a semi-drying condition, which will not disintegrate
as early as when the oil is thoroughly dried to linoxyn. If this is
true, it would seem advisable to use with hard-drying pigments, a
proportion of some oil that is semi-drying in nature or one which will
leave a film not too hard. Soya bean oil, wood oil, and fish oil present
themselves as candidates for such use. How they will work in practice,
however, is a question not yet determined. On the other hand, it is well
known that these pigments require enormous quantities of oil in order to
grind to a working consistency, and it is possible that the life of
such coatings is due rather to the property of these pigments, of taking
up large quantities of oil, than to their effect upon the slow drying of
oil. Excessive oil carrying, however, should be avoided, as shown by the
early failure and pitting of those carbon black and lampblack paints
ground with very large quantities of oil, as is the usual practice. When
these carbon and lampblack pigments were ground with barytes (which is a
heavy pigment and requires only about 9 pounds of oil to 100 pounds of
pigment, as against 175 pounds of oil to 100 pounds of lampblack), it
was found that the lampblack and carbon black paints were reinforced and
made more suitable for actual practice. The stimulative nature of these
black pigments, however, asserted itself in both cases, and large
pittings and eruptions were evident at the end of a year. Carbon black,
lampblack, graphite, or any other good conductor of electricity should
never be placed next to the surface of iron. They are good as
top-coatings, but not as prime-coaters. Some pigments are stimulators of
corrosion, because they contain water-soluble impurities that hasten the
rusting, while others, like graphite, hasten it simply because, being
good conductors, they stimulate surface electrolysis.
=Panel No. 20--Willow Charcoal.= In excellent condition throughout.
Presence of small quantities of potash may be responsible for the
inhibitive nature of this black pigment.
=Panel No. 24--Ochre.= While the film seems intact, it has a very
mottled appearance and examination shows eruptions of rust through the
film, in several places.
=Panel No. 27--Natural Barytes.= Within a year the film became
pin-holed, and corrosion was apparent. At the end of three years very
little of the pigment was left upon the plate, having chalked and scaled
off. Barytes has proved its usefulness as a constituent of a combination
type of paint, but it should not be used alone.
=Panel No. 28--Blanc Fixe.= In the same condition as Panel No. 27, but
slightly more chalking and disintegration was shown.
[Illustration: Panel Painted with Blanc Fixe. Right Side Stripped of
Paint to Show Corrosion]
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