Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
[Illustration: Scaled Whiting Films
Chemically Active Pigments and Their Effect After Eighteen Months'
Wear]
[Illustration: Plate Showing Effect of Chemically Active Pigments on Oil
after One Year's Wear]
=Panel No. 29--Whiting.= Plates coated with calcium carbonate or whiting
in oil presented a very fair appearance at the start of the test, but
they soon began to chalk and disintegrate. It is well known that
whiting, being alkaline, has the property of acting on oil and causing
its early disintegration by saponification. As a matter of fact, six
months after the whiting plates were exposed, crumbling of the surface
appeared, and twelve months was sufficient for the total destruction of
the paint. At this time the rusted surface of the plates which had been
painted with calcium carbonate, seemed not to rust as fast as those
plates which were exposed without paint coatings, and the rust which had
formed appeared to be of an even, fine texture. On the lower left-hand
corner of these plates had been lettered the figures "29" and "30,"
using lampblack in oil. One of the most remarkable things which appears
on the fence to-day is the perfect condition of these lampblack letters
over their priming coat of calcium carbonate, standing out in clear
relief against the rusted metal. This test would suggest, therefore,
that if the surface of metal is properly protected with a pigment which
is slightly alkaline or inhibitive in nature, and then topped with a
good weather-resisting material, such as lampblack, graphite or carbon
black, good results would be obtained. Further tests will be made to
determine the value of this suggestion.
=Panel No. 30--Precipitated Calcium Carbonate.= Showed more rapid
destruction than Panel No. 29.
[Illustration: Corrosion Adhering to Film Stripped from Panel Painted
with Gypsum (Calcium Sulphate)]
=Panel No. 31--Calcium Sulphate.= Under the paint film of gypsum, rust
soon appeared, showing that the film was not a good excluder of
moisture. Although the film remained intact, rusting progressed
throughout the test and considerably darkened the color of the paint.
=Panel No. 32--China Clay.= This pigment gave excellent service for
eighteen months. Afterwards indications of corrosion were shown, and
apparent breakdown of the film was indicated.
[Illustration: China Clay
Asbestine
Gypsum]
=Panel No. 33--Asbestine.= In the same condition as Panel No. 32.
[Illustration: Excellent Surface shown by American Vermilion after
nearly Four Years' Exposure]
=Panel No. 34--American Vermilion.= This pigment has given perfect
protection to the plates. The film is strong and elastic, and upon
removal reveals the bright steel. No chalking, checking, discoloration,
or other signs of paint failure are shown. It would appear that the
inhibitive characteristics of this pigment are pronounced, and it
promises to give efficient service for several years more.
Public-domain text, read in full here on John Shaqi.
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