Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
1. Soya bean oil 120
2. Linseed oil 102
3. Calcium sulphate 93
4. Barytes 88
5. Asbestine 74
6. Corroded white lead 59
{ Basic carb.--White lead 25% }
{ Basic sulph.--White lead 20% }
7. { Zinc oxide 25% } 58
{ Calcium sulphate 25% }
{ Calcium carbonate 5% }
8. Sublimed white lead 56
9. Zinc oxide 56
{ Zinc lead white 30% }
10. { Zinc oxide 40% } 42
{ Basic carb.--White lead 20% }
{ Calcium carbonate 10% }
11. { Basic carb.--White lead 50% } 42
{ Zinc oxide 50% }
{ Basic carb.--White lead 38% }
12. { Zinc oxide 48% } 38
{ Silica 14% }
The test boards were then exposed, with their content of water, to the
action of the sun's rays. Blistering of the painted surfaces took place
in many cases, caused by the rapid withdrawal of the water and its
consequent action on the paint film. The tests seem to indicate that a
mixture of white lead and zinc oxide, with or without a small percentage
of the inert pigments, is not as subject to the action of the water as
the single pigment paints. In order, however, to corroborate these
tests, it occurred to the writer to develop a more visible means of
demonstrating the passage of moisture through paint films.
[Illustration: Bell Jar Apparatus for Testing Permeability of Paint
Films
Paint films sealed over mouths of Bottles containing Lime Water.
Carbonic Acid Gas generated under Bell Jar passes through Plate Films
and precipitates Calcium Carbonate]
Another series of white pine boards were therefore soaked in a solution
of iron sulphate for several hours. After removal, the surface of each
board was dried and coated with one coat of the paints previously
tested. After thorough drying for forty-eight hours, there was placed on
the surface of each board a few drops of a solution of potassium
ferrocyanide. This solution has the effect of producing a blue
coloration with iron sulphate, and in every case when it was placed on a
paint of considerable porosity, the solution penetrated through and
formed a blue coloration beneath the paint. The results corroborated the
original tests referred to above.
A series of sheets or films of paints were then prepared according to
the method referred to on page 71. These films were placed over glass
dialyzing cups, allowing the inner surfaces to sag so as to hold a small
amount of dilute ammonium chloride solution. Distilled water was placed
on the reverse side of the dialyzing apparatus and the tests started. At
the end of six days the distilled water in each test was examined and
the following results obtained:
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