Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=Menhaden Oil.= Of all the marine-animal oils, such as seal, herring,
sardine, whale, and menhaden, the latter is the most valuable. It is
produced by steam digestion and pressure of the menhaden or "piogey"
fish, which are caught in great quantities off the Atlantic Coast.
Prompt cooking and treatment of the fish results in a light-colored oil
having very little odor, the residue left in the presses being of great
value as a fertilizer. Although several grades of oil termed crude,
brown, light, etc., are produced, the most satisfactory for use in paint
is that grade termed "light winter pressed." This oil is of a pale straw
color and has a high iodine number which is responsible for its rapid
drying value. It contains less of the stearates that precipitate from
crude oil, but sufficient to render its film water-shedding and elastic.
The presence of too great a quantity of stearates is apt to result in a
very soft film, and the use of hard driers, such as the metallic
tungates, is therefore advisable with menhaden oil. When mixed with
linseed oil paints the odor of menhaden oil is sometimes noticeable, but
it disappears entirely after such paints are applied. Its use with
linseed oil in technical paints exposed to the salty air of the Coast
has given good results, often preventing "checking" and "chalking."
The following constants were determined on samples of menhaden oil
received in the writer's laboratory:
========+==========+==========+==============+==========
| Sp. Gr. | Iodine |Saponification| Acid
| | Value | Number | Number
--------+----------+----------+--------------+----------
Light | .927 | 175.8 | 187.9 | 7.55
Medium | .925 | 178.7 | 187.6 | 6.19
Dark | .927 | 178.0 | 187.3 | 7.19
========+==========+==========+==============+==========
=Whale Oil.= While ordinary whale oil is too dark and odorous to ever
come into extensive use as a paint oil, it is probable that the refined
oil will be utilized in the manufacture of certain technical paints.
Whale oil is boiled from chopped whale blubber, the first trying being
the lightest in color, while the later tryings, as well as the product
made from bones, are of darker color and of very bad odor. Oil of
mirbane is often used to mask this odor. The oil contains large
quantities of stearin and palmitin, as well as wax-like constituents
which are apt to be thrown out of solution in very cold weather, or when
the oil is mixed with other oils. The refined oil, when ground with lead
and zinc pigments and mixed with equal parts of linseed oil and treated
tung oil, dries to an elastic and soft film. Experiments are being made
to utilize whale oil in the linoleum industry.
The analyses of samples of whale oil tested by the writer are as
follows:
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