Pharmacologia: Fourth American, from the Seventh London EditionParis, John Ayrton
Science
Pharmacologia: Fourth American, from the Seventh London Edition
Paris, John Ayrton
Pharmacognosy; Pharmacology; Pharmacy
QUALITIES. _Form_, a dry mass composed of minute crystals, not
deliquescent; _Colour_, bluish green. CHEMICAL COMPOSITION. Several
constituents enter into its composition, viz. Acetate and sub-acetate of
copper, carbonate of copper, and copper partly metallic and partly
oxidized; it contains also the stalks of grapes and other extraneous
substances. SOLUBILITY. Boiling water dissolves it in part, and produces
in it a chemical change, by transforming one portion of the
_sub_-acetate into the soluble acetate, and another into an oxyd of
copper, which is precipitated; with cold water this substance demeans
itself differently, the acetate is dissolved by it, whilst that portion
which is in the state of _sub_-salt remains suspended in the form of a
fine green powder. Vinegar converts all the _Ærugo_ into a soluble
acetate, this liquid therefore ought never to be employed for favouring
vomiting in cases where an overdose has been swallowed, for the reasons
stated in the first part of this work, p. 136. Sulphuric acid poured on
powdered _verdigris_ decomposes it with effervescence, and vapours of
acetic acid are disengaged. It appears from the experiments and
observations of Duval and Orfila, that sugar exercises a chemical action
on it, by which its solubility is diminished, and that on this account
it acts as a specific against its poisonous effects. USES. It is so
uncertain and violent in its operation that it is rarely employed,
except externally,[358] when it acts as a powerful detergent, and mild
escharotic; and in the form of ointment, is a valuable application for
many cutaneous affections, especially the aggravated kinds of Tetter.
OFFICINAL PREPARATIONS. _Ærugo Præparata_, D. _Linimentum Æruginis._ L.
D. ADULTERATIONS. There is a spurious article sold under the name of
_English Verdigris_, which consists of sulphate of copper, triturated
with acetate of lead; and to make the fraud still more complete, the
soft mass is mixed with the stalks of Raisins.
ÆTHER SULPHURICUS RECTIFICATUS. L.
_Rectified Sulphuric Æther._
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