Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.Various
History
Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.
Various
Science -- Periodicals
2. Solutions of iron in the vitriolic acid, or of common green vitriol
in water, which totally throw down gold, happily made no change in
solutions of platina. Compositions of platina and gold being dissolved
in aqua-regis, the solutions diluted with about twice their quantity
of water, and a filtered solution of the vitriol gradually added; the
mixtures instantly grew turbid, and, on standing, deposited the gold
in form of a purplish grey calx, the whole of the platina remaining
dissolved. It appeared, on numerous repetitions of this experiment,
that no part of the platina was precipitated along with the gold, nor
any of the gold kept suspended with the platina. Where the quantity of
the mixt to be assayed was very small, the precipitation was usually
performed in a filter, that the gold, which separates in very minute
moleculæ, some of which might possibly remain unobserved in the bottom
of a glass, might be detained on the paper. The colourless sorts of
filtering-paper are preferable for this use to the coloured; as these
last may be impregnated with astringent matter, which would extricate
some of the ferrugineous part of the vitriol. The vitriol was dissolved
in about six times its quantity of water, and a few drops of oil of
vitriol added, to prevent the separation of any of its iron in the
filter. This solution was put into the filter first, the solution of
gold and platina immediately poured into it, the whole stirred together
with a clean glass rod, and such part of the liquor, as had run thro’
before they had been duly mixed, poured back to the rest. The gold
remaining in the filter was washed with fresh parcels of water, the
paper cautiously rolled up, and burnt in a crucible, as mentioned in a
former experiment.
3. Solutions of the vitriol, recommended by Kunckel and others for
precipitating gold of an uncommonly high colour, made no change in
the solutions either of gold or platina. The bluish green did indeed
precipitate the gold; not as blue vitriols, but by virtue of the
ferrugineous matter, of which these kinds largely participate. White
vitriol was likewise made trial of, but without producing any sensible
effect in either solution.
4. The experiments with green vitriol were repeated on the solutions of
platina and gold made in spirit of salt. The event was the same as with
those made in aqua-regis; the gold being constantly precipitated, and
the platina remaining dissolved.
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