Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.Various
History
Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.
Various
Science -- Periodicals
3. The experiment was repeated likewise with the subtile fluid,
prepared from vinous spirits with the vitriolic acid, called by the
chemists æther. The separation succeeded in the same manner as before;
the æther receiving nothing from pure platina, but instantly taking up
the gold from a mixture of the two. It is observable, that the gold
imbibed by this fluid is kept permanently dissolved by it; without
separating or reviving, as it does from the common essential oils and
vinous spirits.
4. The liquors remaining in these experiments, after the extraction of
the gold, appear on all trials the same with the common solutions of
platina; and readily betray their being impregnated with that mineral
by their colour, by the precipitation with tin, by their yielding
a sparkling red precipitate with volatile spirits, _&c._ A far more
minute proportion of platina, mixed with gold, is more distinguishable
by these processes, than by those with alkaline salts above-mentioned;
these exhibiting the whole of the platina dissolved by itself, those
only a part of it.
4. _By metallic Solutions._
All the metals, which precipitate gold from aqua-regia, have been
already shewn to precipitate platina also. As gold is thrown down
by some metallic solutions, as well as by the metals in substance,
particularly those of mercury and iron, it remains to apply these
liquors as precipitants for platina.
1. A saturated solution of mercury in aqua-fortis, which readily and
totally threw down gold in its metallic form, being added to a solution
of platina, the liquor became immediately turbid, and, on standing for
a little time, nearly the whole of the platina fell to the bottom. A
solution of mercury in the marine acid, or of corrosive sublimate,
likewise precipitated platina, but less perfectly, and with this
difference, that the former precipitate was of a greyish brown colour,
the latter of a sparkling red.
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