Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.Various
History
Philosophical transactions, Vol. L. Part I. For the year 1757.: Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world.
Various
Science -- Periodicals
31. The same solution, being mixed with syrup of violets, became of a
reddish colour.
32. Saccharum Saturni being added to the solution, precipitated a thick
lactescent cloud.
33. Ol. tart. p.d. being also added to this solution, it caused no
visible effervescence, yet raised some bubbles of air, and caused a
coagulation of many small brown terrene nubeculæ in the water; which,
after standing some time, subsided to the bottom, and left the water
clear.
These experiments do plainly evince, that this water contains an
aluminous salt, conjoined with a fine terrene substance, which is
probably a part of the matrix, from whence the salt has been formed.
This salt gives no signs of any alkaline principle; but, on the
contrary, of an acidity, as its solution reddens with syrup of violets.
With this salt there are also intimately conjoined some very subtile
chalybeat parts, which are not separable from it by elixation or
evaporation.
Alum is distinguishable from all other mineral salts, by liquifying
and bubbling upon a red-hot iron, and turning into a white calx. But
this could not be well expected from this aluminous salt, which we
had extracted from the water, because it was extremely foul, by being
combined with so large a proportion of earth; which earthy parts were
the occasion of turning the salt of a blackish colour upon the iron.
However, we see it turns white by a further degree of heat. But if the
salt had been dissolved, filtrated, and crystallized, till it had been
purified and freed from this terrene matter, it would then certainly
have had the same appearance upon the red-hot iron, as a pure aluminous
salt. Again, as it is peculiar to an aluminous salt to liquify in some
degree with fire, so we see, that this was evidently the case of this
salt. Its eliquation indeed could not be so remarkable, as in pure
alum, because of its being mixed with so much earth; but that it did
liquify in some degree is plain, because the whole mass of salt and
earth, even when reduced to a powder, ran all together like a cinder.
The experiment upon the solution of this salt with ol. tart. p.d.
is also a further proof of what we have already asserted: for tho’
there was no visible effervescence, yet the bubbles of air shew, that
there was an intestine conflict of the oil with the acid principle
in the solution; which being absorbed by the alkali, the earth was
precipitated, to which it formerly adhered.
The two next experiments were made in order to discover, whether an
acid or alkaline principle prevailed in the water.
_Exp._ 34. Forty gutts of the syrup of violets being added to an ounce
of the water, the mixture became of a bright sea-green colour.
35. A quantity of water being kept boiling for five minutes, and
afterwards allowed to stand till it became clear, was carefully
filtrated from its ochrous sediment: after which, upon its mixture with
syrup of violets, it turned of a faint reddish colour.
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