=21. Cohesion and Adhesion.=--In liquids "the molecules move about
freely yet tend to cling together." This tendency of molecules to cling
together which is not noticeable in gases is characteristic of =liquids=
and especially of =solids=. It is the cause of the viscosity mentioned
in the previous section and is readily detected in a variety of ways.
For instance, not only do liquid molecules cling together to form drops
and streams, but they cling to the molecules of solids as well, as is
shown by the wet surface of an object that has been dipped in water. The
attraction of like molecules for one another is called _cohesion_, while
the attraction of =unlike molecules= is called _adhesion_, although the
force is the same whether the molecules are alike or unlike. It is the
former that causes drops of water to form and that holds iron, copper,
and other solids so rigidly together. The adhesion of glue to other
objects is well known. Paint also "sticks" well. Sometimes the "joint"
where two boards are glued together is stronger than the board itself.
The force of attraction between molecules has been studied carefully.
The attraction acts only through very short distances. The attraction
even in liquids is considerable and may be measured. The cohesion of
water may be shown by an experiment where the force required to pull a
glass plate from the surface of water is measured.
[Illustration: FIG. 9.--The water is pulled apart.]
Take a beam balance and suspend from one arm a circular glass
plate, Fig. 9. Weigh the plate and its support. Adjust the glass
plate so that it hangs horizontally and just touches the surface of
clean water, the under side being completely wet. Now find what
additional weight is required to raise the glass plate from the
water.
Just as the plate comes from the water its under side is found to be
wet. That is, _the water was pulled apart_, and the plate was not pulled
from the water. The cohesion of the water to itself is not so strong as
its adhesion to the glass.
The cohesion of liquids is further shown by the form a drop of liquid
tends to take when left to itself. This is readily seen in small drops
of liquids. The spherical shape of drops of water or mercury is an
example. A mixture of alcohol and water in proper proportions will just
support olive oil within it. By carefully dropping olive oil from a
pipette into such a mixture, a drop of the oil, an inch or more in
diameter suspended in the liquid, may be formed. It is best to use a
bottle with plane or flat sides, for if a round bottle is used, the
sphere of oil will appear flattened.
[Illustration: FIG. 10 _a_.
FIG. 10 _b_.
FIGS. 10 _a_ AND _b_.--Surface tension of a liquid film.]
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