Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Silica 51·21
Iron protoxide 20·72
Magnesia 6·16
Water 4·49
Alumina 7·25
Soda 6·21
Manganese protoxide trace.
While a Cyprus earth showed:--
Per cent.
Silica 51·5
Iron protoxide 20·5
Magnesia 1·5
Water 8·0
Potash 18·0
The presence of copper would point suspiciously to adulteration, and in
any case should suffice to condemn the sample for use.
Naturally there is considerable variety of tint among the many kinds
of terre verte, but they all belong to the pale greyish class, and are
more or less translucent, consequently their covering power is small.
Their value lies in their durability, and the resistance they offer to
the injurious effects of strong light and impure atmosphere. They can
be employed either as oil or water colours. The only preparation to
which the natural pigments are submitted is fine grinding and washing.
TITANIUM GREEN.--An excellent dark green pigment, though
rather costly, can be prepared from rutile or any titaniferous iron ore
by the following method:--
The ore is dressed clean, and fused with twelve times its weight of
acid sulphate of potash in a crucible. When cool, it is reduced to
fine powder, and digested at 120° F. in dilute hydrochloric acid (half
water) until solution is complete. The hot solution is filtered off
from the residue and carefully evaporated down to a syrupy consistence,
when the nearly pure titanic acid is allowed to cool in the dish and
thrown on a filter. When sufficiently drained, it is boiled in a large
volume of water containing a little ammonia, and the precipitated
titanic acid is filtered and washed.
If an ore is used containing carbonate of lime, it must first be
treated with dilute hydrochloric acid before the sulphate of potash is
applied.
The titanic acid on the filter is next mixed with a concentrated
solution of sal ammoniac, and again filtered. Then it is digested
in dilute hydrochloric acid at 120° to 140° F. till the solution is
complete. On adding ferrocyanide of potassium to the acid liquor,
and bringing quickly to a boil, a precipitate of ferro-cyanide of
titanium is thrown down. This is very carefully and slowly dried, at a
temperature never exceeding 200° F.
VERDIGRIS.--The chemical examination of verdigris shows it to
be a basic hydrated acetate of copper, containing variable proportions
of the bibasic and tribasic acetates.
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