Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Commercially it is prepared in districts where acetic or pyroligneous
acid can be had at small cost. Thin pieces of scrap copper are
subjected to the action of fermenting grape skins in mass, or cider
refuse, for a fortnight or three weeks; or to the influence of
pyroligneous acid for four or five days. By this means the copper
surfaces are attacked by the acetic acid being generated or liberated,
and become coated with acetate of copper. At intervals the pieces
are removed, and surfaces are cleaned of the accumulated acetate or
verdigris and this is repeated till the metallic copper has thus been
completely converted. The collected verdigris is washed, and carefully
dried at a very low temperature.
Its composition is subject to many irregularities, and the colour
varies from green to bluish green according to the proportion of
sesquibasic acetate present. It is one of the least permanent pigments,
especially in the presence of water, and is exceedingly poisonous.
At one time it was largely used as a pigment, but is now gradually
going, if indeed it has not already gone, out of use. It can be
distinguished by its solubility in acids and ammonia, the latter giving
a deep azure blue solution. On being heated, it turns black, owing to
its parting with acetic acid and leaving the black oxide of copper
behind. This should be entirely soluble in nitric acid, the solution
giving the characteristic tests for copper. The solution should give
no precipitate with chloride of barium or nitrate of silver, and the
original pigment should be freely soluble in any acid and in ammonia
without effervescence.
VERDITER.--Green verditer is another of the copper greens
which has practically disappeared from the modern painter’s list of
pigments. It is a yellow tinted very fugitive colour, consisting of
a basic carbonate of copper, and is manufactured by treating copper
solutions with carbonate of soda, or of potash.
VERONA EARTH.--One kind of terre verte (see p. 134), is known
by this name because it is produced in the neighbourhood of Verona.
VICTORIA GREEN.--This is a fancy name for the Brunswick greens
compounded from Prussian blue, and already described on p. 114.
VIENNA GREEN.--The aceto-arsenite of copper described under
the heading of emerald green (see pp. 121-125), is sometimes called by
this name.
ZINC GREEN.--The pigments described under cobalt green (see
p. 119), as often pass by the name of zinc greens, and in fact they
contain much more zinc than cobalt.
A handsome but not permanent green may be made by combining zinc
with iron instead of cobalt, in the form of a double cyanide. The
process is as follows:--Finely powdered Prussian blue is stirred into
a concentrated solution of chloride of zinc, and put by to allow
the decomposition to take place. After some time, the precipitated
ferro-zinc cyanide is thoroughly washed, and dried out of reach of the
light.
CHAPTER VI.
REDS.
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