Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(1) Buisson prepares three solutions: [_a_] a neutral solution of
protochloride of tin by dissolving 1 part of tin in hydrochloric acid;
[_b_] a solution (bichloride) of 2 parts of granulated tin in an aqua
regia containing 3 parts of nitric to 1 of hydrochloric acid, removing
the excess of acid; [_c_] a neutral solution of 7 parts of gold in an
aqua regia composed of 1 part of nitric and 6 parts of hydrochloric
acid. The gold chloride solution is largely diluted with water, and to
it is added the solution _b_ of bichloride, and finally the solution
_a_ of protochloride is introduced, a drop at a time, until the
desired colour is produced in the precipitate. This last is rapidly
washed by decantation, and finally dried away from the light.
(2) Figuier prepares a gold bichloride solution by dissolving 20
grammes of gold in 100 grammes of an aqua regia containing 4 parts
of hydrochloric to 1 of nitric acid. The solution is evaporated to
dryness in a water bath, and the residue is dissolved in 750 grammes of
water. Into this solution, when duly filtered, pure granulated tin is
introduced, and the whole is left for some days, at the end of which
time all the gold will be in the state of stannate of protoxide; it is
collected on a filter, carefully washed, and gently dried. The residues
contain some gold, and should be preserved for subsequent operations.
CHINESE RED.--One of the many names of the chromate of lead
pigment, described under Derby red, see p. 145.
CHROME ORANGE.--A popular name for the group of yellow-red
pigments consisting essentially of lead chromate, and described under
Lead orange, on p. 147.
CHROME RED.--Another of the synonyms for Derby red, see p. 145.
COBALT PINK.--This costly and permanent artists’ colour is
a combination of oxide of cobalt with magnesia. It is prepared by
treating carbonate of magnesia with a concentrated solution of nitrate
of cobalt; the resulting paste is dried in a stove, calcined in a
porcelain crucible, and finally ground to a fine powder.
COBALT RED.--A very deep-coloured and permanent red pigment
used in oil painting is the arseniate of cobalt, which is found
native in admixture with other substances in cobalt mines, or may be
artificially produced.
The native mineral is treated with boiling nitric acid; the solution
is filtered clear, and small portions of potash are added till all
the iron has been thrown down as arseniate. After this is completed,
the mass is allowed to settle, and the clear liquor is poured off.
On adding further small portions of potash, the cobalt is also
precipitated as arseniate.
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