Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
On the industrial scale the operation is conducted in a large tub,
which receives the mixture of pulp and caustic lye in precisely the
proportions found by experiment to give the best results. The changes
in colour soon manifest themselves, and the whole reaction is completed
in about 12 hours. At the end of that time, the lye is drawn off, and
carries with it much of the chromic acid. The precipitated pigment
is carefully washed with pure water once in the tub, and the mass is
gently stirred. The washing is continued in the filters by throwing
water upon the pulp, and in this manner there is less friction between
the crystals, which retain their deep colour. Of course a highly
crystalline dark red cannot possess great covering power.
(2) Prinvalt mixes together 100 lb. of lead carbonate and 30½ lb. of
potash bichromate neutralised with caustic potash, in 50 gallons of
water, leaving them in contact for a couple of days under repeated
agitation. About half an hour’s boiling then suffices to develop the
red colour. After settling, the supernatant liquor is drawn off, and
the precipitated pigment is washed twice with pure water and finally
with acidulated water (1 lb. sulphuric acid in 10 gallons of water),
and dried.
There are several other recipes published which differ in detail from
(2), but they do not demand a lengthy description.
(3) 100 lb. of lead carbonate (white lead) made into a paste with
water, then added to and boiled with a solution of 50 lb. of potash
bichromate and 15 lb. of caustic soda of 77 per cent. Remainder of
process as before.
(4) 4 cwt. of lead monoxide (litharge) and 60 lb. of salt dissolved
in 50 gallons of water, and left with agitation for 4 or 5 days; then
boiled for 2 hours with solution of 150 lb. of potash bichromate.
(5) 100 lb. of lead carbonate (white lead) made into a paste with
water, then added to a solution of 30 lb. of potash bichromate and 12½
lb. of caustic soda at 77 per cent., and boiled.
Derby red possesses great covering power and considerable brilliancy;
but if not very carefully washed it is liable to retain a little
alkali, which renders it unstable. Otherwise, it well resists damp,
strong light, and impure air so long as sulphuretted hydrogen is
absent. Taken altogether it is not one of the best red pigments, and
its consumption is declining.
INDIAN RED.--This is one of the names for the red pigments due
to oxide of iron, and is described under oxide red, p. 150.
Public-domain text, read in full here on John Shaqi.
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