Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(1) The practice in France, as carried on near Tours, at the white lead
works using the Thénard process, is to calcine the best metallic lead
in reverberatory furnaces built in the rock. These furnaces are five
in number, with double fireplaces, four being constantly in operation,
dealing with about 4000 lb. at a charge, and using bituminous coal as
fuel. Each furnace is nearly circular in shape and about 11 feet in
diameter, with a fire-place on each side of the hearth. The latter is
constructed of fire-brick containing as little silica as possible,
and is made hollow so as to retain the metallic lead when the heat has
rendered it fluid.
The products of combustion from the side fire-places, having heated
the hearth and its contents, pass through an aperture in front of the
charging door of the hearth, and thence go to furnish heat to an upper
hearth where the conversion of the oxide into red lead takes place.
A period of about 12 hours is occupied in the oxidation of a charge,
which is repeatedly “rabbled.” Even then a considerable amount of the
metallic lead remains unoxidised and is returned to the calciner with
the next charge. Half the oxide is utilised for making white lead, as
described in a later chapter, and the other half is converted into red
lead by the method detailed hereunder.
The crude oxide is pulverised in a small mill and separated from the
unconverted metal. The mill takes the form of a flat circular cast-iron
plate on which rotates a cast-iron muller. Water and an agitating
arrangement are also provided.
As the muller revolves the material undergoes comminution, and the
small particles of oxide as formed are disturbed by the agitator and
kept in suspension in the water, by the overflow of which they are
continuously carried away into settling pits. The residual metallic
lead is not pulverised, and of course never becomes suspended in the
water, consequently it accumulates at the bottom of the mill, whence it
is occasionally withdrawn for re-calcination.
Sufficient oxide having collected in the settling pits, it is
transferred to a shallow pan heated by the waste heat from the furnaces
and is there rendered almost dry. In this state it is put into small
square dishes made of sheet iron, and adapted to hold about 30 lb. each.
A charge consists of a hundred of these dishes, which are placed in
the heated furnaces at the end of each day. The roasting is repeated
several times, and the product is accordingly known as “two fires,”
“three fires,” &c. The material at this stage is lumpy and coarse,
and has to undergo dry pulverisation, the fine particles as they are
produced being drawn off by means of a pneumatic fan, and collected.
Public-domain text, read in full here on John Shaqi.
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