Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(2) What may in contradistinction be called the English method of
making minium does not differ materially from the preceding. The
“drossing” furnace, where the metallic lead is first oxidised, receives
a smaller charge as a rule, and perhaps greater care is given to the
rabbling, and to the regulation of the temperature so that it is only
just above the melting point of the metallic lead, and not sufficient
to fuse the massicot.
Minium or red lead is one of the most important and useful red
pigments, as it mixes well with oil, has good covering power, dries
quickly, and is permanent except in presence of sulphur or sulphides.
ORANGE MINERAL.--The pigment known as orange mineral or
orange lead is simply minium which has been imperfectly calcined.
Consequently it is almost identical with red lead in composition,
qualities, and method of manufacture, the only exception being that,
as the calcination is not carried quite so far, therefore the colour
is not so fully developed, and is an orange rather than a red. As with
minium, practically the only adulterant is iron oxide red, which may be
detected by boiling the pigment to a colourless solution with nitric
acid, when addition of prussiate of potash will give a blue precipitate.
OXIDE REDS.--Under various names--such as Persian red, light
red, Indian red, scarlet red, rouge, colcothar, red oxide, purple
oxide, &c.--many pigments, of which the base is the ferric oxide
Fe_{2}O_{3}, are now made. These vary in shade from a deep scarlet red
to a dark violet. They are obtained both from natural and artificial
sources. Oxide of iron occurs naturally as the mineral hematite, and
some varieties of this are bright enough and soft enough to be used as
pigment when ground up. These are usually nearly pure oxide of iron.
Then the ochres, when calcined, yield red pigments known as light red,
Indian red, &c., and a good many reds are obtained from this source.
The composition of these is variable, being dependent upon that of the
ochres from which they are made, and these, as has already been pointed
out, vary very much. Then, in preparing fuming sulphuric acid from
copperas, oxide of iron which is specially sold as rouge, is obtained.
Colcothar is produced as a residue; this is nearly pure oxide of iron,
and usually has a red colour. In the manufacture of sulphuric acid from
pyrites, a dark violet oxide of iron is left as a residue, and much of
this is used as a pigment under the name of purple oxide. Then a large
quantity of oxide of iron reds are made artificially from waste liquors
obtained in copper refining, galvanising iron, &c. The composition of
the oxide of iron reds, therefore, is very variable.
The whole group of oxide reds is of foremost importance, by reason of
their good colour, covering power, and durability, besides which, being
mostly bye-products of much more important manufactures, their cost is
reasonable.
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