Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The actual composition of vermilion is 100 parts of mercury to 16 of
sulphur, when both these ingredients are in a perfectly pure state;
the excess of 5⅓ lb. of sulphur added by the Chinese is probably
volatilised and lost in the process of sublimation, or, as the sulphur
used is generally not quite pure, a part may go for foreign matter
contained in the sulphur; the balance being probably the _raison
d’être_ of the blue lambent flame seen playing over the apertures
in the luting during the sublimation process. For a people having,
like the Chinese, no acquaintance with even the first rudiments of
chemistry, the proportion of ingredients taken--56¼ catties to 13
catties, or say 75 lb. to 17⅓ lb.--shows wonderfully accurate powers
of observation and a knowledge of combining proportions only to be
gained by much experience and a long extended series of careful
observations highly creditable to the manufacturers. The entire process
is one of the most ingenious and interesting to be seen in any part of
the world.--(T. I. B.)
Another and briefer account of the Chinese vermilion manufacture is
given by H. Maccallum, in the Proceedings of the Pharmaceutical Society.
He says there are three vermilion works in Hong Kong, the method of
manufacture being exactly the same in each. The largest works consume
about 6000 bottles of mercury annually, and it was in this one that the
following operations were witnessed:--
First Step.--A large, very thin iron pan, containing a weighed
quantity, about 14 lb., of sulphur, is placed over a slow fire, and
two-thirds of a bottle of mercury added; as soon as the sulphur begins
to melt, the mixture is vigorously stirred with an iron stirrer until
it assumes a black pulverulent appearance with some melted sulphur
floating on the surface; it is then removed from the fire and the
remainder of the bottle of mercury is added, the whole being well
stirred. A little water is now poured over the mass, which rapidly
cools it; the pan is immediately emptied, when it is again ready
for the next batch. The whole operation does not last more than ten
minutes. The resulting black powder is not a definite sulphide, as
uncombined mercury can be seen throughout the whole mass; besides, the
quantity of sulphur used is much in excess of the amount required to
form mercuric sulphide.
Public-domain text, read in full here on John Shaqi.
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