Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Second Step.--The black powder obtained in the first step is placed
in a semi-hemispherical iron pan, built in with brick, and having
a fireplace beneath, covered over with broken pieces of porcelain.
These are built up in a loose porous manner, so as to fill another
semi-hemispherical iron pan, which is then placed over the fixed one
and securely luted with clay, a large stone being placed on the top
of it to assist in keeping it in its place. The fire is then lighted
and kept up for sixteen hours. The whole is then allowed to cool. When
the top pan is removed, the vermilion, together with the greater part
of the broken porcelain, is attached to it in a coherent mass, which
is easily separated into its component parts. The surfaces of the
vermilion which were attached to the porcelain have a brownish red and
polished appearance, the broken surfaces being somewhat brighter and
crystalline.
Third Step.--The sublimed mass obtained in the second step is pounded
in a mortar to a coarse powder, and then ground with water between
two stones, somewhat after the manner of grinding corn. The resulting
semi-fluid mass is transferred to large vats of water and allowed to
settle, the supernatant water is removed, and the sediment is dried
at a gentle heat; when dried, it is again powdered, passed through a
sieve, and is then fit for the market.--_Proc. Pharm. Soc._
(4) Firmenich describes a process which he declares gives better
results in the beauty of colour than any other. It consists in using
sulphide of potassium, which must be in a state of great purity. Of the
various methods for preparing potassium sulphide, Firmenich rejects
those in which caustic potash lye is boiled with excess of flowers of
sulphur, on account of the simultaneous formation of a hyposulphite
or sulphate of potash, which interferes in the preparation of the
vermilion.
The process adopted by Firmenich for making pure potassium sulphide is
to reduce sulphate of potash by heating with charcoal, and subsequently
saturating the lye with sulphur to the necessary degree.
Usually about 20 parts by weight of potassium sulphate and 6 parts
by weight of charcoal are reduced to very fine powder and thoroughly
incorporated. Placed in a Hessian crucible, the mass is covered,
luted, and strongly heated. As considerable ebullition takes place
the crucible should be of such a size that the charge only occupies
two-thirds of its capacity. After fusion is complete, the mass,
which is now potassium sulphide, is allowed to cool; it presents a
reddish-brown crystalline appearance, and is very hygroscopic. It is
put into a cast-iron pan, with addition of soft water in the proportion
of 7 parts of water to every 2 parts of the potassium sulphide; after
boiling, it is filtered and on cooling, the undecomposed sulphate of
potash collects in crystals attached to the sides of the pan.
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