Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The construction of a stack is a very simple and rude operation. Layers
of dung or tan, or a mixture of the two, are so arranged as to imbed
a large number of earthenware pots, each containing some acetic acid.
These pots are about 4 or 5 inches in diameter, and about 7 or 8 inches
high; a coil of lead is placed in each pot, and buckles or gratings of
lead supported on oaken bearers are laid across and on top of the pots;
boards are laid to cover the whole, and form a floor.
The stack is composed of a number of such layers of pots, bearers, and
buckles or gratings, raised one upon another.
A stack chamber is a brick enclosure 10 or 12 feet square, and 20 or
25 feet high; such a chamber will contain about 70 tons of lead when
stacked and piled. In a white lead factory several of these chambers
are built side by side, and when they are in full operation a set of
chambers will contain as much as 700 or 1000 tons of lead.
Only the purest kind of lead will be suitable for conversion in
this stack process of making white lead, the common varieties being
inadmissible. Messrs. Pontifex and Wood have furnished the following
analyses of lead used for white lead making.
Copper. Antimony. Iron. Spelter. Silver. Lead.
A 0·00700 0·00490 0·00200 0·00080 0·00100 99·98430
B 0·07580 0·00320 0·00220 0·00320 0·00200 99·91360
C 0·00340 0·00460 0·00120 0·00070 0·00350 99·98660
D 0·05260 0·00740 0·00150 0·00180 0·00400 99·93270
E 0·00940 0·00210 0·00160 0·00100 0·00075 99·98515
F 0·02360 0·00580 0·00210 0·00180 0·00100 99·96570
The presence of silver, copper and iron in the lead would damage the
colour of the white lead resulting, and other admixtures retard or
prevent the progress of conversion.
In olden times horse dung was the only imbedding material used in
the stack arrangement. This material when heated evolves gases which
seriously interfere with the colour of the resulting corrosion. Dung
has been almost superseded in this country by tanners’ refuse; in
Belgium dung is yet employed, and in some places a mixture of dung and
tan.
Where dung is used, the process of corrosion of the lead goes on more
quickly than when tan alone is employed, but the use of tan offers
great advantages, especially this one: that it does not give off gases
that damage the white lead.
The operations of charging and discharging these chambers are
principally the work of women, and are most laborious and fatiguing.
In emptying the chambers and stripping the stacks, the women are fully
exposed to the heated gases which are yielded by the decomposing tan,
and the heated and corroded lead. These gases, in themselves most
injurious to health, are not to be compared in this respect to the dust
which pervades the air and fills the chamber in which these women work.
Public-domain text, read in full here on John Shaqi.
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