Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The stacks are generally allowed to remain in operation, after they
are charged, three or four months; in this time it is presumed all
profitable action in the stack has ceased. The temperature of the
stack, which had risen gradually from the normal temperature to 100°
or 150° F., will have gradually fallen, and this falling temperature
is the indication that the corrosion of the lead in the stack has
terminated.
After the three months’ action of the stacks, they are stripped and
pulled to pieces. Some will be found to be done better than others, and
one part of the same stack will be done more perfectly than another.
The coating on the lead will also differ; some will be smooth, regular,
and equal in formation, some will be rough and blistered, and far from
uniform. The rough blistered casting is rejected as unfit for white
lead making: the workmen call it “dross.” The smooth laminated coating
is the one preserved for the after manufacture.
It is a curious fact connected with the consideration of the total
want of educated guidance in these matters that prevails, that in all
factories of this description some chambers are noted as always working
well, and others are equally well known to always do their work the
reverse of well. No one knows why! No one stays to seek the reason.
The factory way goes on filling and emptying these white lead chambers
whether the stacks be working well or no.
The incrustation that is most esteemed by the manufacturers of white
lead in this old-fashioned style is a hard, china-like material, formed
of thin deposits, layer upon layer, in a slow, continuous, regular way.
It is at once conceivable that in the rough-and-ready manner of stack
manufacture most irregular action must proceed.
It would be almost impossible for the contents of the pile or stack to
be submitted to the same action of the gases throughout. Some parts of
the stack and its contents will be under more favourable conditions
than others, hence the reason why, in practice, it is invariably
found that some stacks, and some parts of a stack, work better than
others. Under the microscope, this good crust of white lead, the proper
incrustation from which to prepare white lead, will be readily seen
to consist of very thin coatings or layers of white lead, which have
been slowly formed on the metallic lead and piled one upon another to
the thickness of an eighth or a quarter of an inch. This formation
constitutes the hard, china-like substance, which alone possesses the
chemical constitution and the properties to form good white lead paint.
Public-domain text, read in full here on John Shaqi.
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