Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
white lead will be made up of one part of hydrate and two parts of
carbonate of lead.
The second compound roughly estimated
Pb H_{2}O_{2},3Pb CO_{3}
will be one part of hydrate, combined with three parts of carbonate
or lead. The latter will be in the proportion of 75 per cent, of
carbonate and 25 per cent, of hydrate of lead, and this represents the
composition which has been assigned to good white lead by those most
acquainted with the subject. The amount of hydrate contained in white
lead should never exceed the proportion above named of 25 per cent.,
nor should its amount be much below the 25 per cent.
The hydrate contained in the substance serves to unite with the oil in
the paint; it forms therewith a drying white and elastic varnish which
embraces and holds the particles of white carbonate and prevents their
subsidence and separation in the paint. There is a chemical action of a
much more intimate character between the components of good white lead
when mixed with oil which neither of the constituents of this compound
can alone produce.
For instance, hydrate of lead and linseed oil produce a varnish-like
substance, semi-transparent and of no covering capability.
Carbonate of lead and linseed oil produce a compound which is opaque,
but has no body or covering power, and in which the white solid
carbonate is held in feeble mechanical suspension.
Neither of them constitutes a paint, but when together as white lead
they are mixed with oil, combination takes place, and serviceable paint
of good body and covering power and enduring quality is produced. Good
white lead is a dense, perfectly amorphous powder of perfect whiteness,
possessed of great body and covering power when combined with oil. When
mixed with linseed oil and used as paint it rapidly dries in the air
and assumes a varnish-like, glossy, hard surface, and is capable when
once dry of resisting the action of air and water for any length of
time. It does not weep when laid on a surface with a brush, that is,
the oil does not separate from the solid material of the paint.
Attempts have been made to produce white lead quickly and cheaply by
precipitating processes, but in all such methods the resulting compound
is deficient in certain special qualities absolutely necessary to white
lead proper and to its uses. The precipitated white lead is always of
a crystalline structure, and crystalline lead can never furnish a good
body paint--no amount of pulverising and grinding of this crystalline
material will correct this defect in its nature, and deprive it of its
crystalline form.
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