Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Dry powdered white lead is chiefly made for and used by grinders
and mixers, who combine with it a variety of other cheaper
materials--chalk, clay, sulphate of lime, and sulphate of baryta, but
principal use is made of chalk and barytes. These are mixed with the
white lead, and then the mixture is ground with oil and formed into
paint, sold under various names according to quality: thus--guaranteed
white lead, firsts, seconds, thirds, and fourths, the proportion of
white lead diminishing, and that of the adulterant increasing, as we
descend from the pure material. Guaranteed and best white lead is
not pure, and does not mean pure white lead. Pure white lead can be
purchased at some makers, but its price, if pure, can never fall below
19_l._ or 20_l._ per ton.
To sophisticate white lead, and produce the various inferiors named,
dry powdered white lead is needed as a starting point, and for this
purpose principally arises the necessity for its production. If ground
in oil the adulterants cannot be properly incorporated with it. Dry
white lead is used for nothing else that could ever give rise to any
great demand for it. We have already observed that the production of
this dry and powdered white lead is the most dangerous proceeding
connected with this industry. Grinding in oil is unattended with any
important consequence to the health and comfort of those employed. A
serious drawback to the “stack” production, the china-like incrustation
to which reference has already been made, is that it requires crushing,
grinding, washing, and drying, and a second course of dry grinding
after it is dried--the most objectionable step in its preparation.
Could the corrosion of the blue lead be effected in such a way as to
prevent any discoloration of the material by the tan and wood--could
the corrosion be so produced as to be easily separated from the buckle
or grating on which it has formed--could this separation be so effected
as to prevent the breaking up of the lead skeleton, and the presence
of small pieces of metal in the detached crust of white lead, two
principal reasons for washing and drying are removed.
There is yet another consideration, that is, the presence of acetate
of lead, always found in varying quantities in the incrustation
produced, and remaining at the close of the operation and conversion.
To remove this, careful washing, and after-stoving and drying must be
accomplished. The amount of this salt present is found to differ with
each operation, and in various portions of the same make.
The washing out of the acetate is never perfect, and it involves a
large amount of labour.
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