Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The following variation may be made from the method described of making
tribasic acetate of lead, thus:--To each 60 lb. of acid and 750 lb. of
water may be added sufficient of the tribasic solution to make neutral
acetate of lead, with which to recommence the manufacture of tribasic
acetate of lead by the process described. Vague reference has been made
in works on technical chemistry to the possibility of using metallic
lead in the manufacture of sugar of lead, but such references have been
practically worthless, as they contain no information of a practical
nature even for the manufacture of neutral acetate of lead, and no
process at all has ever been described for the manufacture of basic
acetate of lead from metallic lead acted on by acetic acid or acetate
of lead.
_Gardner’s Process._--The conditions observed and fulfilled in the
arrangements adopted by Prof. E. V. Gardner, are founded upon a study
of the nature, properties and behaviour of the substances concerned,
under certain methods of treatment.
There are several oxides of lead which may be formed under special
conditions.--(1) Pb_{2}O, and the same oxide combined with water
Pb_{2}H_{2}O_{2}; (2) PbO, and the same oxide combined with water
PbH_{2}O_{2}. In the hydrated form these oxides combine readily with
carbonic acid, but they do not combine readily with carbonic acid when
dehydrated. The hydrates are most readily formed at about 120°-130° F.,
and are decomposed after they are formed if heated to 212° F.
These oxides and their hydrates combine with acetic acid to form
acetate and sub-acetate of lead, and with nitric acid to form nitrate
and sub-nitrate of lead.
Lead, submitted to the action of air, watery vapour, and acetic or
nitric acid, or a mixture of these acids, with air or oxygen, with
proper precautions, forms sub-acetate or sub-nitrate of lead, and this
sub-acetate or sub-nitrate of lead readily absorbs carbonic acid and
forms carbonate and sub-carbonate of lead.
Sufficient acetic or nitric acid, or a mixture of these and air or
oxygen, and watery vapour, must be constantly supplied to form the
subsalts of lead, to carry on the operation of converting blue lead
into white lead; but an excess or an insufficiency of these agents will
in either case prevent the formation of sub-acetate or sub-nitrate, and
consequently of the sub-carbonates.
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