Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Thus--too little air, acetic acid and aqueous vapour prevents the
formation of the hydrated sub-acetate and consequently sub-carbonate
of lead. Too much acetic acid and aqueous vapour, and too little air
forms an acetate on the surface of the lead, which, by the excess of
water, dissolves and wastes, and washes the lead; it also varnishes
the surface of the lead with a coating of acetate, and checks, if it
does not completely prevent, the formation of sub-acetate of lead, and
consequently the formation of carbonate and sub-carbonate of lead.
Similar rules hold good in the case of nitric acid and the formation of
nitrate and sub-nitrate.
The process of forming the hydrated sub-acetate or sub-nitrate of
lead is most energetic at a temperature of 120°-130° F. In a lower
temperature, a much longer time is occupied in carrying out the process
of conversion; while at a higher temperature the delicate sub-acetate
or sub-nitrate of lead first formed suffers loss of water, until, at
212° F., it is completely dehydrated. At a temperature about 135° F.,
the power of forming carbonate and sub-carbonates is lessened, and at
212° F. is considerably diminished. The carbonate itself is dehydrated
at 212° F., and is decomposed at a higher temperature.
To obtain a white lead of excellent quality for its various uses, it
is necessary to produce a substance which possesses sufficient body to
cover surfaces to which it may be applied as paint, and it must possess
sufficient base to combine with the oil of the paint to form a vehicle
or varnish to retain and hold the body on the surface. This is found to
be the case with sub-carbonate of lead, or especially with a compound
constituted of two or three equivalents of carbonate of lead, with one
equivalent of hydrated oxide of that metal.
Lead, to be attacked by chemical agents, should possess a clean
surface. If the surface of the lead is _chemically_ clean, so much the
better. The surface of the lead should be extended as much as possible,
and exposed to the action of the gases and vapours at a certain heat
for its conversion into white lead.
If the most favourable conditions are sought, the temperature should
be between 120° and 130° F.; and to carry on the chemical action
most satisfactorily, the lead during its conversion should present a
granular coating--that is, the coating formed by the chemical agents
should be granular and not smooth and continuous in character. It
should be porous, and not of a continuous varnish-like or vitreous
character.
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