Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Owing to these difficulties in purifying carbonic acid, Prof. Gardner
prefers to prepare a practically pure carbonic acid in the first place,
and this he does by allowing petroleum, benzine, paraffin, or other
hydrocarbon or carbonaceous liquid to gradually fall into a retort
containing chalk or other suitable carbonate at a high temperature,
whereby relatively pure carbonic acid gas is generated; and while still
in a highly heated state it encounters a stream of air or oxygen,
ensuring its complete combustion before entering the converting chamber.
Another method of procuring fairly pure carbonic acid is by the
combustion and oxidation of any of the liquid hydrocarbons mentioned
above, in suitable lamps; and when carbonic acid gas of exceptional
purity is required, it may be obtained by heating bicarbonates to a
sufficient degree to drive off one molecule of carbonic acid, reducing
the bicarbonate to carbonate, from which it can be reproduced by
treatment with carbonic acid gas obtained from cheaper sources.
The _modus operandi_ adopted by Prof. Gardner is as follows: The
lead is granulated and prepared for conversion in one operation,
thus--an iron or a slate slab about 2-3 inches thick is placed in a
tank containing acetic or nitric acid solutions rising about 3 inches
above the upper surface of the slab. The lead is melted at low red
heat and poured from a height of 4 to 6 feet into the acid solution,
through which it falls till it encounters the slab, and thereupon
passes away into the surrounding solution, being thus converted into
a spongy condition. In this condition the lead is spread on frames or
trays, which are then lifted bodily into their places in the converting
chambers. The latter is closed and heated to 120° F. for 3-4 hours, or
until the whole contents have assumed a uniform temperature. Thereupon
the acid vapours and air are admitted and distributed, taking care that
the temperature is not thereby reduced below 110° F. nor increased
above 125° F., steam being temporarily shut off if necessary. This
treatment is continued for 24 hours.
The admission of aqueous vapour should be so regulated that while a
dry atmosphere is avoided, yet there is no appreciable condensation of
moisture in the chamber. While ensuring this condition, the temperature
may reach as high as 130° F. for a second period of 24 hours, but must
not overstep the limits of 120° F. minimum and 135° F. maximum.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account