Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The blue lead is arranged in the converting chamber in trays, or on
shelves or frames, so as to allow it to be completely surrounded and
attacked by the vapours or gases, and thereby be converted into white
lead, at the same time preventing the formation of direct currents
or eddies. Framed supports resembling a dinner waggon serve well for
holding the lead, and may easily be arranged to lift bodily in and out
of the chamber with their burden of blue or white lead. The surface on
which the blue lead is directly supported is made of graphitic carbon,
hard coke, platinum, or carbonised or platinised material, such as is
used for plates in electric batteries, or of other material standing
in a similar electrical relationship to lead, or capable of generating
with it an electric current.
In applying this development of electrical energy to the ordinary
“stack,” as for instance the Dutch process, the pots containing
the acetous liquid and blue lead are made of, or lined with, such
electrical carbon, or contain a portion of it in suspension, by which
the same effect is realised. Advantage may also be derived from
furnishing a supplementary supply of carbonic acid to the stack beyond
that due to the decomposing dung, &c.; as well as from injecting
a current of air or oxygen at suitable temperatures, and from the
admission of steam in a coil throughout the stack.
The generation or production of the acetic or nitric acid vapours is
attained by heat in a vessel so arranged that its contents are kept
at a certain temperature for vaporising, by having the boiling acid
solution at about 1·003 sp. gr., procured by mixing water with vinegar
or acetic or nitric acids.
The supply pipes conveying the air or oxygen and the carbonic acid, or
either of them, can easily be made to emit their contents close to the
boiling acid solution, whereby the vapours arising from the latter are
mixed and intermingled with them, and all pass together through the
pipes and distributors into the converting chamber or stack.
In preparing the carbonic acid it is necessary to observe certain
precautions, especially that it shall be pure and that no carbonic
oxide shall gain admission to the chamber. If the ordinary chalk and
carbon method be employed, the furnace must be provided at the uptake
with a series of air inlets, so as to ensure that the gases passing
from the furnace to the delivery tube shall be most thoroughly oxidised.
The purification of the carbonic acid may be effected in the usual way
by passing it through a vessel containing water; or, if requisite, it
may be cleansed, expanded, and heated in one operation by passing it
through or over hot water, or over a hot aqueous solution of carbonate
of soda, all of which, however, incur considerable cost in plant and
manipulation.
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