Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The process is described as follows:--A furnace, 36 in. by 30 in., and
48 in. deep, contracting to a narrow chamber about 36 in. long by 14
in. wide, communicating with the main flue, is charged with coke and
brought to a red heat. The bed of coke is so thick as to be almost
up to the level of the sill of the furnace door. The lead ore is not
charged in large quantity and left for an indefinite time, but is
thrown in in quantities of a few shovelfuls at a time, the object being
to effect extremely rapid volatilisation and consequent oxidation. The
proportion of ore to fuel is 1 ton to 1 ton, and the result is said to
be the conversion of 95 per cent. of the charge into its equivalent
in white lead. In the first or wide chamber, the coke is oxidised,
carbonic oxide being the resulting gas, the rapid volatilisation of
the galena or sulphide of lead also taking place in the same chamber.
On entering the inner portion of the furnace, the volatilised sulphide
of lead and the carbonic oxide are converted into carbonic acid and
sulphate of lead.
Forced blast has been employed to cause the high temperature necessary
for the volatilisation of the ore; but it has been found unnecessary,
admission of air at atmospheric pressure through tuyere holes being
quite adequate. After leaving the inner chamber of the furnace, the
gases pass into a flue, level with the furnace, and about 40 feet long
by 16 square feet in sectional area. From this flue the gases pass into
a tower about 20 feet high, and from thence into wrought-iron flues 3
feet in diameter. These flues terminate in a wrought-iron chest, in
which are fitted two steam injectors. The gases are forced by these
injectors into the central chambers of the condensers. These condensers
are two in number, and contain a central chamber, 16 feet by 12 inches,
into which the gases are forced as described. The gases escape through
interstices into the outer chambers of the condenser, and are there
condensed, a continuous stream of water occupying the lower part of
the condenser. The waste gases escape by a downcast leading to a tall
chimney. The temperature of the gases as they enter the condenser is
about 840° F.
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