Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The product is pumped from the condensers to a settling vat. Here it
settles for an hour, the deposit being pumped into a second vat and
washed with dilute sulphuric acid, in order to remove impurities. The
resulting product is washed several times with water, and is then
passed through a filter press. From the press it drops into bogies,
which carry the pulp to the drying house, where it is dried by hot air.
The process would thus appear an extremely simple and practical one.
Several chemical authorities of repute, as well as manufacturing firms
and others who have used the new white lead, have expressed themselves
strongly as to its merits. One point immensely in favour of sulphate
of lead as opposed to carbonate, is that the former is almost entirely
innocuous, whereas the poisonous properties of the other are well
known. It is claimed that the sulphate is not acted upon by coal gas or
by the atmosphere of towns, which is always more or less impregnated
with gases such as sulphuretted hydrogen, whose reactions with various
metals have only too good reason to be known.
According to the patent specification bearing the names of French and
Hannay, they employ lead ores, lead fume, or lead slags containing
sulphur; and when these materials do not contain sufficient sulphur to
form a sulphate with all the lead which sublimes in the process, they
add to them pyrites or other sulphur-yielding substance to make up the
deficiency. They heat the materials mixed with a suitable proportion
of coke in an air-blast cupola furnace, which is by preference of
an improved and special construction shown in Figs. 18 to 20, and
hereinafter described; and they thereby produce sulphite of lead as a
sublimate, provided that there are no chlorides such as common salt
present in the charge, in which case sulphate and chloride of lead will
be formed.
The sublimate is carried forward with the current of gases through
flues to a fume condenser, which is by preference of the kind known
as Wilson’s and French’s. As the gases and sublimate pass through the
flues, hydrochloric acid is mixed
[Illustration: Fig. 18.
Fig. 19.
Fig. 20.
FRENCH AND HANNAY’S WHITE-LEAD FURNACE.]
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